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In mildly alkaline medium, thiosulphate ...

In mildly alkaline medium, thiosulphate ion is oxidized by `MnO_(4)^(-)` to "A". The oxidation state of sulphur in "A" is ______

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To solve the problem, we need to determine the oxidation state of sulfur in the product formed when thiosulfate ion (S₂O₃²⁻) is oxidized by permanganate ion (MnO₄⁻) in a mildly alkaline medium. ### Step-by-Step Solution: 1. **Identify the Reactants and Products**: - The reactant is thiosulfate ion (S₂O₃²⁻). - The oxidizing agent is permanganate ion (MnO₄⁻). - In a mildly alkaline medium, thiosulfate will be oxidized to sulfate ion (SO₄²⁻). 2. **Determine the Oxidation State of Sulfur in the Product**: - The product formed is sulfate ion (SO₄²⁻). - We need to find the oxidation state of sulfur (S) in sulfate. 3. **Set Up the Oxidation State Equation**: - Let the oxidation state of sulfur in sulfate be \( x \). - The sulfate ion has four oxygen atoms, each with an oxidation state of -2. - The overall charge of the sulfate ion is -2. The equation can be set up as follows: \[ x + 4(-2) = -2 \] 4. **Solve the Equation**: - Simplifying the equation: \[ x - 8 = -2 \] \[ x = -2 + 8 \] \[ x = +6 \] 5. **Conclusion**: - The oxidation state of sulfur in the product sulfate (SO₄²⁻) is +6. ### Final Answer: The oxidation state of sulfur in "A" (sulfate) is **+6**. ---
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