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What type of structural isouters are [Co...

What type of structural isouters are `[Co(NH_3)_5Br]SO_4 and Co[(NH_3)_5SO_4]Br` ? Give a chemical test to distinguish the isomers.

Text Solution

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`underset("I")([Co(NH_(3))_(5)Br]SO_(4))andunderset("II")([Co(NH_(3))_(5)SO_(4)]Br)` are Ionization isomer.
When the two isomers are treated with slightly acidic `BaCl_(2)` solution
`[Co(NH_(3))_(5)Br]SO_(4)` produces white ppt. `(BaSO_(4))` but `[Co(NH_(3))_(5)SO_(4)]Br` does not.
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