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In the equation CH(3)COOH+Cl(2)overset("...

In the equation `CH_(3)COOH+Cl_(2)overset("RedP")underset(-HCl)rarrA`, the compound A is :

A

`CH_(3)CH_(2)Cl`

B

`ClCH_(2)COOH`

C

`CH_(3)Cl`

D

`CH_(3)COCl`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze the reaction between acetic acid (CH₃COOH) and chlorine (Cl₂) in the presence of red phosphorus and hydrochloric acid (HCl). The goal is to determine the compound A that is produced from this reaction. ### Step-by-Step Solution: 1. **Identify the Reactants**: The reactants in the equation are acetic acid (CH₃COOH) and chlorine (Cl₂). 2. **Understand the Role of Red Phosphorus and HCl**: Red phosphorus and HCl facilitate the reaction by generating chlorine gas from Cl₂. This chlorine gas will then participate in the substitution reaction. 3. **Identify the Structure of Acetic Acid**: Acetic acid has the following structure: \[ \text{CH}_3 - \text{C(=O)OH} \] The carbon atom adjacent to the carboxylic group (C(=O)OH) is known as the alpha carbon, and it has three alpha hydrogens. 4. **Recognize the Halogenation Reaction**: When a carboxylic acid with alpha hydrogens reacts with chlorine in the presence of red phosphorus and HCl, the alpha hydrogen can be substituted by a chlorine atom. This is a characteristic reaction known as the H-V-Z reaction (Hunsdiecker-Van Zanden reaction). 5. **Perform the Substitution**: In this case, one of the alpha hydrogens in acetic acid will be replaced by a chlorine atom. The reaction can be represented as follows: \[ \text{CH}_3 - \text{C(=O)OH} + \text{Cl}_2 \rightarrow \text{CH}_3 - \text{C(=O)Cl} + \text{HCl} \] The product formed is **alpha-chloroacetic acid** (CH₂ClCOOH). 6. **Write the Final Product**: The compound A produced from the reaction is: \[ \text{Compound A: CH}_2\text{ClCOOH (alpha-chloroacetic acid)} \] ### Final Answer: The compound A is **alpha-chloroacetic acid (CH₂ClCOOH)**. ---
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