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For the redox reaction MnO(4)^(ө)+C(2)...

For the redox reaction
`MnO_(4)^(ө)+C_(2)O_(4)^(2-)+H^(o+)rarrMn^(2+)+CO_(2)+H_(2)O`
the correct coefficients of the reactions for the balanced reaction are

A

`2,5,16`

B

`16,5,2`

C

`5,16,2`

D

`2,16,5`

Text Solution

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The correct Answer is:
To balance the redox reaction: \[ \text{MnO}_4^{-} + \text{C}_2\text{O}_4^{2-} + \text{H}^{+} \rightarrow \text{Mn}^{2+} + \text{CO}_2 + \text{H}_2\text{O} \] we will follow these steps: ### Step 1: Identify Oxidation States - For \(\text{MnO}_4^{-}\), the oxidation state of Mn is +7. - For \(\text{C}_2\text{O}_4^{2-}\), the oxidation state of carbon is +3. - In \(\text{Mn}^{2+}\), the oxidation state of Mn is +2. - In \(\text{CO}_2\), the oxidation state of carbon is +4. ### Step 2: Determine the Half-Reactions - **Reduction Half-Reaction**: \[ \text{MnO}_4^{-} + 8\text{H}^{+} + 5\text{e}^{-} \rightarrow \text{Mn}^{2+} + 4\text{H}_2\text{O} \] - **Oxidation Half-Reaction**: \[ \text{C}_2\text{O}_4^{2-} \rightarrow 2\text{CO}_2 + 2\text{e}^{-} \] ### Step 3: Balance the Half-Reactions - The reduction half-reaction is already balanced in terms of atoms and charge. - The oxidation half-reaction needs to be multiplied by 5 to balance the number of electrons: \[ 5\text{C}_2\text{O}_4^{2-} \rightarrow 10\text{CO}_2 + 10\text{e}^{-} \] ### Step 4: Combine the Half-Reactions Now we can combine the balanced half-reactions: - Multiply the oxidation half-reaction by 5: \[ 5\text{C}_2\text{O}_4^{2-} \rightarrow 10\text{CO}_2 + 10\text{e}^{-} \] - The reduction half-reaction remains the same: \[ 2\text{MnO}_4^{-} + 8\text{H}^{+} + 10\text{e}^{-} \rightarrow 2\text{Mn}^{2+} + 4\text{H}_2\text{O} \] ### Step 5: Add the Half-Reactions Adding both half-reactions gives: \[ 2\text{MnO}_4^{-} + 5\text{C}_2\text{O}_4^{2-} + 16\text{H}^{+} \rightarrow 2\text{Mn}^{2+} + 10\text{CO}_2 + 8\text{H}_2\text{O} \] ### Final Balanced Equation The balanced equation is: \[ 2\text{MnO}_4^{-} + 5\text{C}_2\text{O}_4^{2-} + 16\text{H}^{+} \rightarrow 2\text{Mn}^{2+} + 10\text{CO}_2 + 8\text{H}_2\text{O} \] ### Coefficients The correct coefficients for the balanced reaction are: - \(2\) for \(\text{MnO}_4^{-}\) - \(5\) for \(\text{C}_2\text{O}_4^{2-}\) - \(16\) for \(\text{H}^{+}\) ### Answer Thus, the answer is \(2, 5, 16\). ---

To balance the redox reaction: \[ \text{MnO}_4^{-} + \text{C}_2\text{O}_4^{2-} + \text{H}^{+} \rightarrow \text{Mn}^{2+} + \text{CO}_2 + \text{H}_2\text{O} \] we will follow these steps: ...
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