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According to the moleular orbital theory...

According to the moleular orbital theory, all atomic orbitals combine to form molecular orbital by `LCAO` (linear combination of atomic orbitals) method When two atomic orbitals have additive (constructive) method When two atomic orbitals have additive (constructive) overlapping they form bonding molecular orbitals `(BMO)` which have lower energy than atomic orbitals whereas when atomic orbitals overlap subtractive higher energy antibonding molecular orbitals `(ABMO)` are formed Each `MO` occupies two electrons with opposite spin Distribution of electrons in `MO` follows Aufbau principle as well as Hund's rule `MO` theory can successfully explain the magnetic behaviour of molecules
Bond strength increases when

A

bond order increases

B

bond length increases

C

antibonding electrons increases

D

bond angle increases

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To solve the question regarding the conditions under which bond strength increases, we will analyze the relationship between bond order, bond length, and other factors affecting bond strength. ### Step-by-Step Solution: 1. **Understanding Bond Strength**: - Bond strength refers to the energy required to break a bond between two atoms. It is influenced by the type of bond (single, double, triple) and the atomic orbitals involved. 2. **Bond Order**: - Bond order is defined as the number of bonding electrons minus the number of antibonding electrons, divided by two. - A higher bond order indicates a stronger bond. For example, a triple bond has a bond order of 3, a double bond has a bond order of 2, and a single bond has a bond order of 1. 3. **Relationship Between Bond Order and Bond Strength**: - As bond order increases, bond strength also increases. This is because a higher bond order means more electrons are involved in bonding, which leads to a stronger attraction between the nuclei of the bonded atoms. 4. **Bond Length**: - Bond length is inversely proportional to bond strength. This means that as bond strength increases (due to higher bond order), bond length decreases. A shorter bond length indicates a stronger bond. 5. **Effect of Antibonding Electrons**: - The presence of antibonding electrons (in molecular orbitals) can weaken the bond. Therefore, an increase in antibonding electrons generally leads to a decrease in bond strength. 6. **Bond Angle**: - Bond angle can also influence bond strength. A larger bond angle can indicate less steric strain and a more stable molecular structure, which can correlate with stronger bonds. 7. **Evaluating Options**: - **Option A**: Bond strength increases when bond order increases. (True) - **Option B**: Bond strength increases when bond length increases. (False, as bond length and bond strength are inversely related) - **Option C**: Bond strength increases when antibonding electrons increase. (False, as more antibonding electrons weaken the bond) - **Option D**: Bond strength increases when bond angle increases. (True, as larger bond angles can indicate less strain and more stability) ### Conclusion: The correct options that indicate conditions under which bond strength increases are **A** and **D**.

To solve the question regarding the conditions under which bond strength increases, we will analyze the relationship between bond order, bond length, and other factors affecting bond strength. ### Step-by-Step Solution: 1. **Understanding Bond Strength**: - Bond strength refers to the energy required to break a bond between two atoms. It is influenced by the type of bond (single, double, triple) and the atomic orbitals involved. 2. **Bond Order**: ...
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CENGAGE CHEMISTRY ENGLISH-CHEMICAL BONDING AND MOLECULAR STRUCTURE-Exercises Linked Comprehension
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  2. The HF(2)^(Θ) ion solid state and liquid HF but not in the dilute aque...

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  3. Consider the following molecules . A:Anti -pyridine -2-carboxaldoxime...

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  4. Consider the following molecules . A:Anti -pyridine -2-carboxaldoxime...

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  5. Valence-bond theory is one of the two quantum mechanical approaches th...

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  6. Valence-bond theory is one of the two quantum mechanical approaches th...

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  7. Valence-bond theory is one of the two quantum mechanical approaches th...

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  8. Valence-bond theory is one of the two quantum mechanical approaches th...

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  9. Which of the following statements is correct about O(2),O(2)^(Θ),O(2)^...

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  10. O(2)^(2-) will have .

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  11. According to the moleular orbital theory, all atomic orbitals combine ...

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  12. According to the moleular orbital theory, all atomic orbitals combine ...

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  13. Most of the polyatomic molecules except a few such as CO(2) and CS(2) ...

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  14. Which of the following have highest bond angle ? .

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  15. Which of the following hybridisation may have more than one type of bo...

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  16. Which one of the following statements is correct .

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  17. MO' s are formed by the overlap of A'O s Two AO's combine to form two ...

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  18. MO' s are formed by the overlap of A'O s Two AO's combine to form two ...

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  19. Which one of the following has maximum number of nodal planes ? .

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  20. MO' s are formed by the overlap of A'O s Two AO's combine to form two ...

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