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Assertion (A): A small piece of zinc dis...

Assertion `(A)`: A small piece of zinc dissolves in dilute nitric acid but no hydrogen is evolved.
Reason `(R)` : `HNO_3` is an oxidising acid and oxidises hydrogen evolved to water.

A

If both (A) and (R) are correct and (R) is the correct explanation of (A).

B

If both (A) and (R) are correct but (R) is not the correct explanation of (A).

C

If (A) is correct, but (R) is incorrect.

D

If (A) is incorrect, but (R) is correct.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the assertion and reason question, we will analyze both statements step by step. ### Step 1: Analyze the Assertion The assertion states: "A small piece of zinc dissolves in dilute nitric acid but no hydrogen is evolved." - When zinc (Zn) reacts with dilute nitric acid (HNO3), it typically forms zinc nitrate (Zn(NO3)2) and may produce nitrogen oxides (NO or N2O) instead of hydrogen gas. This is because nitric acid acts as an oxidizing agent. ### Step 2: Analyze the Reason The reason states: "HNO3 is an oxidizing acid and oxidizes hydrogen evolved to water." - Nitric acid (HNO3) is indeed an oxidizing agent. In reactions involving zinc and nitric acid, if hydrogen gas were to be produced, it would be oxidized by the nitric acid to form water (H2O). Thus, the statement about HNO3 oxidizing hydrogen to water is correct. ### Step 3: Conclusion - Both the assertion and the reason are correct. The assertion correctly states that no hydrogen gas is evolved when zinc reacts with dilute nitric acid, and the reason correctly explains that if hydrogen were produced, it would be oxidized to water by the nitric acid. ### Final Answer Both the assertion (A) and the reason (R) are correct, and the reason (R) is the correct explanation for the assertion (A). ---

To solve the assertion and reason question, we will analyze both statements step by step. ### Step 1: Analyze the Assertion The assertion states: "A small piece of zinc dissolves in dilute nitric acid but no hydrogen is evolved." - When zinc (Zn) reacts with dilute nitric acid (HNO3), it typically forms zinc nitrate (Zn(NO3)2) and may produce nitrogen oxides (NO or N2O) instead of hydrogen gas. This is because nitric acid acts as an oxidizing agent. ### Step 2: Analyze the Reason ...
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CENGAGE CHEMISTRY ENGLISH-HYDROGEN, WATER AND HYDROGEN PEROXIDE-Exercises (Assertion Reasoning)
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  4. Assertion (A): A small piece of zinc dissolves in dilute nitric acid b...

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  5. Assertion (A): Hydrogen oxidises lithium to Li. Reason (R) : Hydroge...

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  6. Assertion (A): Pink coloured solution of potassium permanganate turns ...

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  8. Assertion (A): Colour of KMnO4 disappears when dihydrogen gas is bubbl...

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  9. Assertion (A): Concentration of H2O2 is expressed in volume. Reason ...

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  10. Assertion (A): Hardness of water is determined by titrating it with di...

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  11. Assertion (A): Temporary hardness in water is due to the presence of c...

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  12. Assertion (A): When blood is added to a solution of H2O2, the solution...

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  13. Assertion (A): Alkali metals form ionic hydrides. Reason (R) : Alkal...

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  14. Assertion (A): The process of adsorption of hydrogen on palladium is k...

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  15. Assertion (A): H2O is a linear molecule. Reason (R) : Oxygen is sp^3...

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  16. Assertion (A): NaCl is less soluble in heavy water than in ordinary wa...

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