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Assertion (A): Electrolysis of hard wate...

Assertion `(A)`: Electrolysis of hard water produces `O_2` and `D_2`.
Reason `(R)` :Ordinary hydrogen is called protium.

A

If both (A) and (R) are correct and (R) is the correct explanation of (A).

B

If both (A) and (R) are correct but (R) is not the correct explanation of (A).

C

If (A) is correct, but (R) is incorrect.

D

If (A) is incorrect, but (R) is correct.

Text Solution

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The correct Answer is:
To solve the assertion and reason question, we need to analyze both statements carefully. ### Step 1: Analyze the Assertion The assertion states: "Electrolysis of hard water produces O2 and D2." - Hard water is primarily composed of minerals like calcium and magnesium salts. When electrolysis is performed on hard water, it typically produces oxygen gas (O2) at the anode and ordinary hydrogen gas (H2) at the cathode. - Deuterium (D2) is an isotope of hydrogen and is not produced from the electrolysis of ordinary hard water. Instead, deuterium would be produced from the electrolysis of heavy water (D2O). **Conclusion for Assertion**: The assertion is **incorrect** because electrolysis of hard water does not produce D2. ### Step 2: Analyze the Reason The reason states: "Ordinary hydrogen is called protium." - Protium is indeed the most common isotope of hydrogen, represented as H or ¹H. It has one proton and no neutrons. - This statement is accurate and correctly defines what ordinary hydrogen is. **Conclusion for Reason**: The reason is **correct**. ### Final Conclusion - The assertion is incorrect, and the reason is correct. Therefore, the correct option for this question is that the assertion is false, but the reason is true. ### Summary of the Solution - Assertion (A): Incorrect (Electrolysis of hard water produces O2 and H2, not D2). - Reason (R): Correct (Ordinary hydrogen is indeed called protium). - Therefore, the answer is that the assertion is false, and the reason is true. ---

To solve the assertion and reason question, we need to analyze both statements carefully. ### Step 1: Analyze the Assertion The assertion states: "Electrolysis of hard water produces O2 and D2." - Hard water is primarily composed of minerals like calcium and magnesium salts. When electrolysis is performed on hard water, it typically produces oxygen gas (O2) at the anode and ordinary hydrogen gas (H2) at the cathode. - Deuterium (D2) is an isotope of hydrogen and is not produced from the electrolysis of ordinary hard water. Instead, deuterium would be produced from the electrolysis of heavy water (D2O). ...
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CENGAGE CHEMISTRY ENGLISH-HYDROGEN, WATER AND HYDROGEN PEROXIDE-Exercises (Assertion Reasoning)
  1. Assertion (A): Ferrocyanide ion oxidises H2O2 to H2O. Reason (R) : O...

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  2. Assertion (A): In a reaction of H2O2 and Na2CO3, hydrogen peroxide act...

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  3. Assertion (A): The colour of old lead painting can be restored by wash...

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  4. Assertion (A): A small piece of zinc dissolves in dilute nitric acid b...

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  5. Assertion (A): Hydrogen oxidises lithium to Li. Reason (R) : Hydroge...

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  6. Assertion (A): Pink coloured solution of potassium permanganate turns ...

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  7. Assertion (A): Electrolysis of hard water produces O2 and D2. Reason ...

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  8. Assertion (A): Colour of KMnO4 disappears when dihydrogen gas is bubbl...

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  9. Assertion (A): Concentration of H2O2 is expressed in volume. Reason ...

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  10. Assertion (A): Hardness of water is determined by titrating it with di...

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  11. Assertion (A): Temporary hardness in water is due to the presence of c...

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  12. Assertion (A): When blood is added to a solution of H2O2, the solution...

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  13. Assertion (A): Alkali metals form ionic hydrides. Reason (R) : Alkal...

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  14. Assertion (A): The process of adsorption of hydrogen on palladium is k...

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  15. Assertion (A): H2O is a linear molecule. Reason (R) : Oxygen is sp^3...

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  16. Assertion (A): NaCl is less soluble in heavy water than in ordinary wa...

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  17. Assertion (A): Dihydrogen is prepared in the laboratory by the action ...

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