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Paris green was used as a pigment due to...

Paris green was used as a pigment due to unique light green colour but now-a-days it is used as an insecticide. It is prepared by boiling verdigris (basic acetate of copper). Arsenious oxide and acetic acid together. It is

A

`(CH_3COO)_2 Cu.3Cu(AsO_2)_2`

B

Curpric acetoarsenite

C

`Cu_4(CH_3COO)_2(AsO_2)_2`

D

All

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding Paris green and its structure, we will follow these steps: ### Step 1: Identify the Components Paris green is a compound made from verdigris (basic acetate of copper), arsenious oxide, and acetic acid. We need to identify the chemical components involved in its formation. **Hint:** Look for the main ingredients mentioned in the question and their chemical identities. ### Step 2: Understand the Chemical Reaction The reaction involves boiling verdigris, arsenious oxide, and acetic acid together. This implies a chemical reaction where these components combine to form Paris green. **Hint:** Consider how each component contributes to the final product. ### Step 3: Determine the Chemical Formula Paris green is known as cupric acetoarsenite. The chemical formula can be derived from the components: - Verdigris contributes copper (Cu). - Arsenious oxide contributes arsenic (As). - Acetic acid contributes acetate ions (C2H3O2). The overall formula can be represented as: \[ \text{Cu}_3(\text{AsO}_3)(\text{C}_2\text{H}_3\text{O}_2)_2 \] **Hint:** Pay attention to the stoichiometry of the components when writing the formula. ### Step 4: Draw the Structure To visualize Paris green, we need to draw its structure. The structure consists of: - Copper ions (Cu²⁺) coordinated with acetate ions. - Arsenic oxide (AsO₃) as part of the structure. The structure can be represented as: - Three copper ions connected to two acetate ions and one arsenite ion. **Hint:** Use Lewis structures to represent the coordination of copper with acetate and arsenite. ### Step 5: Conclusion The final structure of Paris green (cupric acetoarsenite) can be summarized as a complex of copper, arsenic, and acetate ions. **Hint:** Review the final structure to ensure all components are correctly represented. ### Final Answer Paris green is cupric acetoarsenite, with the formula \[ \text{Cu}_3(\text{AsO}_3)(\text{C}_2\text{H}_3\text{O}_2)_2 \].
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