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Which of the following acids possesses o...

Which of the following acids possesses oxidising, reducing, and complex forming properties ?

A

`HNO_3`

B

`HNO_2`

C

`H_2 SO_4`

D

`HCl`

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The correct Answer is:
To determine which acid possesses oxidizing, reducing, and complex-forming properties, we need to analyze the oxidation states of the elements involved in the given acids. Let's go through the options step by step. ### Step 1: Understand Oxidizing and Reducing Agents - An **oxidizing agent** is a substance that gets reduced (gains electrons) while causing another substance to be oxidized (lose electrons). - A **reducing agent** is a substance that gets oxidized (loses electrons) while causing another substance to be reduced (gain electrons). ### Step 2: Analyze the Given Acids We will analyze the oxidation states of nitrogen in the acids provided: 1. **HNO3 (Nitric Acid)** - Oxidation state of nitrogen = +5 - Since +5 is the maximum oxidation state for nitrogen, it cannot be oxidized further. Therefore, it acts only as an oxidizing agent. 2. **HNO2 (Nitrous Acid)** - Oxidation state of nitrogen = +3 - Nitrogen can be oxidized to +5 (acting as a reducing agent) and can also be reduced to -3 (acting as an oxidizing agent). Thus, HNO2 can act as both an oxidizing and reducing agent. 3. **H2SO4 (Sulfuric Acid)** - Oxidation state of sulfur = +6 - Similar to HNO3, since +6 is the maximum oxidation state for sulfur, it cannot be oxidized further. Therefore, it acts only as an oxidizing agent. 4. **HCl (Hydrochloric Acid)** - Oxidation state of chlorine = -1 - This is the minimum oxidation state for chlorine, so it cannot act as an oxidizing agent. It does not possess reducing properties either. ### Step 3: Conclusion From the analysis: - **HNO3**: Oxidizing agent only. - **HNO2**: Acts as both an oxidizing and reducing agent. - **H2SO4**: Oxidizing agent only. - **HCl**: Neither oxidizing nor reducing agent. Thus, the acid that possesses oxidizing, reducing, and complex-forming properties is **HNO2 (Nitrous Acid)**. ### Final Answer **HNO2 (Nitrous Acid)** possesses oxidizing, reducing, and complex-forming properties. ---
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CENGAGE CHEMISTRY ENGLISH-P-BLOCK GROUP 15 ELEMENTS - THE NITROGEN FAMILY-Exercises (Single Correct)
  1. Nitrates of all metals are

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  2. Following tests are shown by (i) Decolourisation of acidified soln. ...

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  3. Which of the following acids possesses oxidising, reducing, and comple...

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  4. Acidic hydride of nitrogen is

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  5. Among the trihalides of nitrogen, which is the least basic ?

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  6. PCl5 exists but NCl5 does not because :

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  7. PCl5 and PH3 exist but PH5 does not because

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  8. The structure of phosphide ion is similar to that of

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  9. Calcium phosphide is used in smoke screen because it.

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  10. Holme's signals produce burning gases which serve as a signal to the a...

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  11. Among the following the strongest acid is

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  12. Basicity of H3 PO4 and H3 PO3 are

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  13. Phosphoric acid is syrupy in nature due to hydrogen bonding. Each mole...

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  14. PCl3, P4 O6 and P4 O10, PCl5 on hydrolysis gives respectivey.

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  15. If phosphorous acid is allowed to react with sufficient quantity of KO...

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  16. Which one of the following pairs is obtained on heating ammonium dichr...

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  17. By mixing ammonium chloride to potassium nitrite and heating, we get

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  18. In which salt,on heating gives a mixture of two gases is

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  19. Ammonia is not used

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  20. Which one of the following is used for drying of ammonia ?

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