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Which one of the acids is a dibasic acid...

Which one of the acids is a dibasic acid ?

A

`H_3 PO_3`

B

`H_3 PO_2`

C

`HPO_3`

D

`H_3 PO_4`

Text Solution

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The correct Answer is:
To determine which acid is a dibasic acid, we need to analyze the structures and basicities of the given acids. A dibasic acid is defined as an acid that can donate two protons (H⁺ ions) in an aqueous solution. ### Step-by-Step Solution: 1. **Identify the Acids**: The acids we need to consider are: - H₃PO₃ (Phosphorous acid) - H₃PO₂ (Hypophosphorous acid) - H₃PO₄ (Phosphoric acid) - HPO₃ (Metaphosphoric acid) 2. **Analyze H₃PO₃ (Phosphorous Acid)**: - Structure: P(=O)(OH)₂H - It has 2 hydroxyl (OH) groups. - Basicity: The number of acidic hydrogens is 2 (from the two OH groups). - Conclusion: H₃PO₃ is a dibasic acid. 3. **Analyze H₃PO₂ (Hypophosphorous Acid)**: - Structure: P(=O)(OH)H₂ - It has 1 hydroxyl (OH) group. - Basicity: The number of acidic hydrogens is 1. - Conclusion: H₃PO₂ is a monobasic acid. 4. **Analyze HPO₃ (Metaphosphoric Acid)**: - Structure: P(=O)(OH)H - It has 1 hydroxyl (OH) group. - Basicity: The number of acidic hydrogens is 1. - Conclusion: HPO₃ is a monobasic acid. 5. **Analyze H₃PO₄ (Phosphoric Acid)**: - Structure: P(=O)(OH)₃ - It has 3 hydroxyl (OH) groups. - Basicity: The number of acidic hydrogens is 3. - Conclusion: H₃PO₄ is a tribasic acid. 6. **Final Conclusion**: - The only acid among those analyzed that has a basicity of 2 (and thus is dibasic) is H₃PO₃ (Phosphorous acid). ### Answer: The dibasic acid is H₃PO₃ (Phosphorous acid).

To determine which acid is a dibasic acid, we need to analyze the structures and basicities of the given acids. A dibasic acid is defined as an acid that can donate two protons (H⁺ ions) in an aqueous solution. ### Step-by-Step Solution: 1. **Identify the Acids**: The acids we need to consider are: - H₃PO₃ (Phosphorous acid) - H₃PO₂ (Hypophosphorous acid) - H₃PO₄ (Phosphoric acid) ...
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CENGAGE CHEMISTRY ENGLISH-P-BLOCK GROUP 15 ELEMENTS - THE NITROGEN FAMILY-Exercises (Single Correct)
  1. White phophorus reacts with caustic soda, the products are PH(3) and ...

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  2. White phosphorus may be removed from red phosphorus by

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  3. Which one of the acids is a dibasic acid ?

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  4. Which one of the following can be used as an anaesthetic?

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  5. The catalyst used in the manufacture of ammonia by Haber process is

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  6. The catalyst used in the manufacture of NO by Ostwald's process is

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  7. Which of the following properties of white phosphorus are shared by re...

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  8. The number of P-O-P bridges in the structure of phosphorus pentoxide a...

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  9. Nitrogen molecule is chemically less active because of its

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  10. Addition of conc. HNO3 to conc. H2 SO4 gives

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  11. The reaction between NH2^(Ө) and N2 O gives

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  12. Red phosphorus is less reactive than yellow phosphorus because

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  13. Aqua regia is a mixture of

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  14. The number of steps, in which orthophosphoric acid is ionised, are

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  15. Phosphorous is usually extracted from

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  16. PCl5 is kept in well stoppered bottles because

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  17. The BCl3 is a planar molecule whereas NCl3 is pyramidal because

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  18. N2 forms NCl3 whereas P can form both PCl3 and PCl5. Why ?

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  19. Cl-P-Cl bond angles in PCl5 molecule are

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  20. Hydrolysis of NCl3 gives NH3 and X. Which of the following is X ?

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