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PCl5 is kept in well stoppered bottles b...

`PCl_5` is kept in well stoppered bottles because

A

It is highly volatile

B

It reacts readily with moisture

C

It reacts with oxygen

D

It is explosive

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AI Generated Solution

The correct Answer is:
To answer the question of why PCl5 (phosphorus pentachloride) is kept in well-stoppered bottles, we can analyze the options provided and the properties of PCl5. ### Step-by-Step Solution: 1. **Understanding PCl5**: PCl5 is a chemical compound that can react with various substances, including moisture (water vapor) in the air. 2. **Evaluating the Options**: - **Option 1: It is highly volatile**: While PCl5 can sublime, this is not the primary reason for storing it in well-stoppered bottles. - **Option 2: It reacts readily with moisture**: This is a significant property of PCl5. When it comes into contact with moisture, it reacts to form hydrochloric acid (HCl) and phosphoric acid (H3PO4). - **Option 3: It reacts with oxygen**: PCl5 does not have a notable reaction with oxygen that would necessitate special storage. - **Option 4: It is explosive**: PCl5 is not classified as an explosive substance. 3. **Chemical Reaction with Moisture**: The reaction of PCl5 with moisture can be represented as follows: \[ \text{PCl}_5 + \text{H}_2\text{O} \rightarrow \text{H}_3\text{PO}_4 + 5\text{HCl} \] This reaction shows that PCl5 decomposes in the presence of water, producing hydrochloric acid and phosphoric acid. 4. **Conclusion**: To prevent this unwanted reaction with moisture, PCl5 is stored in well-stoppered bottles. This ensures that moisture from the air does not enter the container and react with PCl5. 5. **Final Answer**: Therefore, the correct reason for keeping PCl5 in well-stoppered bottles is that it reacts readily with moisture.

To answer the question of why PCl5 (phosphorus pentachloride) is kept in well-stoppered bottles, we can analyze the options provided and the properties of PCl5. ### Step-by-Step Solution: 1. **Understanding PCl5**: PCl5 is a chemical compound that can react with various substances, including moisture (water vapor) in the air. 2. **Evaluating the Options**: - **Option 1: It is highly volatile**: While PCl5 can sublime, this is not the primary reason for storing it in well-stoppered bottles. ...
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CENGAGE CHEMISTRY ENGLISH-P-BLOCK GROUP 15 ELEMENTS - THE NITROGEN FAMILY-Exercises (Single Correct)
  1. Red phosphorus is less reactive than yellow phosphorus because

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  2. Aqua regia is a mixture of

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  3. The number of steps, in which orthophosphoric acid is ionised, are

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  4. Phosphorous is usually extracted from

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  5. PCl5 is kept in well stoppered bottles because

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  6. The BCl3 is a planar molecule whereas NCl3 is pyramidal because

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  7. N2 forms NCl3 whereas P can form both PCl3 and PCl5. Why ?

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  8. Cl-P-Cl bond angles in PCl5 molecule are

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  9. Hydrolysis of NCl3 gives NH3 and X. Which of the following is X ?

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  10. Chlorine reacts with excess of ammonia to form.

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  11. The following are some statements related to VA group hydrides. I. R...

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  12. The atomicity of white phosphorus is X and the P-P-P bond angle is Y....

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  13. The reaction of P4 with X leads selectively to P4 O6. X is

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  14. Atoms in P4 molecule of white phosphorus are arranged regularly in the...

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  15. Phosphine, acetylene and ammonia can be formed by treating water with

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  16. CN^(Theta) and N(2) are isoelectronic But in contrast to CN^(Theta),N(...

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  17. Nitrogen forms stable N(2) molecule but phosphorus is converted to P(4...

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  18. In NO(3)^(-) ion the number of bond pairs and lone pairs of electrons ...

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  19. Blue liquid which is formed at - 30^@ C by mixing of two gases is.

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  20. The element which forms oxides in all oxidation states +I to +V is

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