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Phosphine, acetylene and ammonia can be ...

Phosphine, acetylene and ammonia can be formed by treating water with

A

`Mg_3 P_2, Al_4 Cl_3, Li_3 N`

B

`Ca_3 P_2, CaC_2, Mg_3 N_2`

C

`Ca_3 P_2, CaC_2, CaCN_2`

D

`Ca_3 P_2, Mg_2 C, NH_4 NO_3`

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The correct Answer is:
To solve the question of how phosphine (PH₃), acetylene (C₂H₂), and ammonia (NH₃) can be formed by treating water with certain compounds, we can analyze the reactions step by step. ### Step 1: Identify the Compounds We need to find which compounds can react with water to produce phosphine, acetylene, and ammonia. The compounds we are considering are calcium phosphide (Ca₃P₂), calcium carbide (CaC₂), and magnesium nitride (Mg₃N₂). ### Step 2: Formation of Phosphine Phosphine (PH₃) can be formed from calcium phosphide (Ca₃P₂) when it reacts with water. The reaction can be written as: \[ \text{Ca}_3\text{P}_2 + 6 \text{H}_2\text{O} \rightarrow 3 \text{Ca(OH)}_2 + 2 \text{PH}_3 \] Here, calcium hydroxide (Ca(OH)₂) is also produced along with phosphine. ### Step 3: Formation of Acetylene Acetylene (C₂H₂) can be formed from calcium carbide (CaC₂) when it reacts with water. The reaction is: \[ \text{CaC}_2 + 2 \text{H}_2\text{O} \rightarrow \text{Ca(OH)}_2 + \text{C}_2\text{H}_2 \] Again, calcium hydroxide is produced along with acetylene. ### Step 4: Formation of Ammonia Ammonia (NH₃) can be formed from magnesium nitride (Mg₃N₂) when it reacts with water. The reaction is: \[ \text{Mg}_3\text{N}_2 + 6 \text{H}_2\text{O} \rightarrow 3 \text{Mg(OH)}_2 + 2 \text{NH}_3 \] Here, magnesium hydroxide (Mg(OH)₂) is produced along with ammonia. ### Step 5: Conclusion From the above reactions, we can conclude that treating water with the combination of calcium phosphide (Ca₃P₂), calcium carbide (CaC₂), and magnesium nitride (Mg₃N₂) will yield phosphine, acetylene, and ammonia. Therefore, the correct answer is option 2. ### Summary of Reactions: 1. **Phosphine Formation**: \[ \text{Ca}_3\text{P}_2 + 6 \text{H}_2\text{O} \rightarrow 3 \text{Ca(OH)}_2 + 2 \text{PH}_3 \] 2. **Acetylene Formation**: \[ \text{CaC}_2 + 2 \text{H}_2\text{O} \rightarrow \text{Ca(OH)}_2 + \text{C}_2\text{H}_2 \] 3. **Ammonia Formation**: \[ \text{Mg}_3\text{N}_2 + 6 \text{H}_2\text{O} \rightarrow 3 \text{Mg(OH)}_2 + 2 \text{NH}_3 \]

To solve the question of how phosphine (PH₃), acetylene (C₂H₂), and ammonia (NH₃) can be formed by treating water with certain compounds, we can analyze the reactions step by step. ### Step 1: Identify the Compounds We need to find which compounds can react with water to produce phosphine, acetylene, and ammonia. The compounds we are considering are calcium phosphide (Ca₃P₂), calcium carbide (CaC₂), and magnesium nitride (Mg₃N₂). ### Step 2: Formation of Phosphine Phosphine (PH₃) can be formed from calcium phosphide (Ca₃P₂) when it reacts with water. The reaction can be written as: \[ \text{Ca}_3\text{P}_2 + 6 \text{H}_2\text{O} \rightarrow 3 \text{Ca(OH)}_2 + 2 \text{PH}_3 \] ...
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CENGAGE CHEMISTRY ENGLISH-P-BLOCK GROUP 15 ELEMENTS - THE NITROGEN FAMILY-Exercises (Single Correct)
  1. Red phosphorus is less reactive than yellow phosphorus because

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  2. Aqua regia is a mixture of

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  3. The number of steps, in which orthophosphoric acid is ionised, are

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  4. Phosphorous is usually extracted from

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  5. PCl5 is kept in well stoppered bottles because

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  6. The BCl3 is a planar molecule whereas NCl3 is pyramidal because

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  7. N2 forms NCl3 whereas P can form both PCl3 and PCl5. Why ?

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  8. Cl-P-Cl bond angles in PCl5 molecule are

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  9. Hydrolysis of NCl3 gives NH3 and X. Which of the following is X ?

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  10. Chlorine reacts with excess of ammonia to form.

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  11. The following are some statements related to VA group hydrides. I. R...

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  12. The atomicity of white phosphorus is X and the P-P-P bond angle is Y....

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  13. The reaction of P4 with X leads selectively to P4 O6. X is

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  14. Atoms in P4 molecule of white phosphorus are arranged regularly in the...

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  15. Phosphine, acetylene and ammonia can be formed by treating water with

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  16. CN^(Theta) and N(2) are isoelectronic But in contrast to CN^(Theta),N(...

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  17. Nitrogen forms stable N(2) molecule but phosphorus is converted to P(4...

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  18. In NO(3)^(-) ion the number of bond pairs and lone pairs of electrons ...

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  19. Blue liquid which is formed at - 30^@ C by mixing of two gases is.

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  20. The element which forms oxides in all oxidation states +I to +V is

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