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An organic reaction occurs by using reag...

An organic reaction occurs by using reagents called electrophiles and nucleophiles via the formation of some reactive intermediates called carbocations, carbanions, free radicals, carbenes, nitrenes, radical cations, and radical anions.
The most stable carbocation is :

A

`Ph overset (oplus) CH_2`

B

C

D

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The correct Answer is:
To determine the most stable carbocation among the given options, we will analyze the stability based on three main factors: hyperconjugation, resonance, and inductive effect. ### Step-by-Step Solution: 1. **Identify the Carbocations**: - Let's denote the carbocations as A, B, C, and D based on the options provided. Each carbocation has a different number of alkyl groups attached to the positively charged carbon. 2. **Understand Hyperconjugation**: - Hyperconjugation refers to the stabilizing interaction that results from the overlap of a σ-bond orbital with an empty p-orbital on the positively charged carbon. The more alkyl groups attached to the carbocation, the more hyperconjugation can occur, leading to increased stability. 3. **Analyze Each Carbocation**: - **Carbocation A**: Has 1 alkyl group (1 α-H). - **Carbocation B**: Has 2 alkyl groups (2 α-H). - **Carbocation C**: Has 3 alkyl groups (3 α-H). - **Carbocation D**: Has no alkyl groups (0 α-H). 4. **Evaluate Stability Based on Hyperconjugation**: - Carbocation A (1 α-H) has limited hyperconjugation. - Carbocation B (2 α-H) has moderate hyperconjugation. - Carbocation C (3 α-H) has the highest hyperconjugation due to the presence of 3 alkyl groups. - Carbocation D (0 α-H) has no hyperconjugation. 5. **Consider Resonance**: - If any of the carbocations can undergo resonance, it will further stabilize the carbocation. However, in this case, we focus primarily on hyperconjugation since the question emphasizes the stability of carbocations. 6. **Conclusion**: - Based on the analysis, Carbocation C, which has the most alkyl groups (3 α-H), is the most stable due to the maximum hyperconjugation effect. ### Final Answer: The most stable carbocation is **Carbocation C**.

To determine the most stable carbocation among the given options, we will analyze the stability based on three main factors: hyperconjugation, resonance, and inductive effect. ### Step-by-Step Solution: 1. **Identify the Carbocations**: - Let's denote the carbocations as A, B, C, and D based on the options provided. Each carbocation has a different number of alkyl groups attached to the positively charged carbon. 2. **Understand Hyperconjugation**: ...
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Reaction intermdiates are short lived species and are highly reactive. They are formed by heterolytic and homolytic bond fission. There are various types of reaction intermediates in which the most important are carbocation , carbanion and free radical. Carbocation is an organic species in which carbon have positive charge and six electrons in its outermost shell. The stability of carbocation can be increased by positive inductive effect, hyperconjugation and delocalisation. If alpha -atom with respect to carbocation has one or more lone pair of electron then lone pair of electron strongly stabilises the carbocation due to octet completion. Species in which carbon have negative charge is called carbanion. Carbanion carries three bond pairs and one lone pair. The stability of carbanion can be increased by negative inductive effect, negative mesomeric effect and delocalisation. Free radical is a species which have seven electrons in its outermost shell. The stability of free radical can be increased by hyperconjugation and delocalisation. The stability order of following carbocations is

Reaction intermdiates are short lived species and are highly reactive. They are formed by heterolytic and homolytic bond fission. There are various types of reaction intermediates in which the most important are carbocation , carbanion and free radical. Carbocation is an organic species in which carbon have positive charge and six electrons in its outermost shell. The stability of carbocation can be increased by positive inductive effect, hyperconjugation and delocalisation. If alpha -atom with respect to carbocation has one or more lone pair of electron then lone pair of electron strongly stabilises the carbocation due to octet completion. Species in which carbon have negative charge is called carbanion. Carbanion carries three bond pairs and one lone pair. The stability of carbanion can be increased by negative inductive effect, negative mesomeric effect and delocalisation. Free radical is a species which have seven electrons in its outermost shell. The stability of free radical can be increased by hyperconjugation and delocalisation. Which of the following is the most stable carbanion intermediate ?

Reaction intermdiates are short lived species and are highly reactive. They are formed by heterolytic and homolytic bond fission. There are various types of reaction intermediates in which the most important are carbocation , carbanion and free radical. Carbocation is an organic species in which carbon have positive charge and six electrons in its outermost shell. The stability of carbocation can be increased by positive inductive effect, hyperconjugation and delocalisation. If alpha -atom with respect to carbocation has one or more lone pair of electron then lone pair of electron strongly stabilises the carbocation due to octet completion. Species in which carbon have negative charge is called carbanion. Carbanion carries three bond pairs and one lone pair. The stability of carbanion can be increased by negative inductive effect, negative mesomeric effect and delocalisation. Free radical is a species which have seven electrons in its outermost shell. The stability of free radical can be increased by hyperconjugation and delocalisation. The stability order of following free radicals is: C_(6)H_(5)underset(I)CH_(2)overset(*)CH_(2)" "CH_(3)underset(II)CH_(2)overset(*)CH_(2)" "underset(" "III)(C_(6)H_(5))overset(*)CH_(2)" "underset(IV)(CH_(3)^(*)

CENGAGE CHEMISTRY ENGLISH-GENERAL ORGANIC CHEMISTRY-Comprehension
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