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Carbene intermediates are produced by th...

Carbene intermediates are produced by the photolysis of diazomethane `(CH_2N_2)` or kenene `(CH_2 = C = O)`. They are also produced by the reaction of `CHX_3` with base or by Simmons-Smith reaction. There are two types of carbenes, singlet and triplet. They are so called due to their spin state.
Singlet and triplet carbene are same in :

A

Types of hybridisation

B

Number of unshared `overline e` pairs (or `LP overline e^, s`)

C

Number of `sigma-bonds`

D

Bond angle

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To solve the question regarding the similarities between singlet and triplet carbenes, we will analyze the properties of both types of carbenes step by step. ### Step-by-Step Solution: 1. **Understanding Carbenes**: - Carbenes are neutral species containing a carbon atom with only six valence electrons, resulting in a divalent state. They can exist in two forms: singlet and triplet. 2. **Singlet Carbene**: - In singlet carbenes, both of the valence electrons occupy the same orbital, leading to a paired state. - Example: The structure of singlet carbene can be represented as R2C: where the colon indicates the lone pair of electrons. 3. **Triplet Carbene**: - In triplet carbenes, the two valence electrons occupy different orbitals, leading to an unpaired state. - Example: The structure of triplet carbene can be represented as R2C with one electron in one orbital and another in a different orbital. 4. **Hybridization**: - Singlet carbenes typically exhibit sp² hybridization, while triplet carbenes can exhibit either sp or sp² hybridization. - Since they differ in hybridization, this means they do not share this property. 5. **Number of Unshared Electron Pairs**: - Both singlet and triplet carbenes have no lone pairs of electrons. However, singlet carbenes have paired electrons, while triplet carbenes have two unpaired electrons. - Therefore, they do not share this property either. 6. **Number of Sigma Bonds**: - Both singlet and triplet carbenes have the same number of sigma bonds. This is a key similarity between the two types of carbenes. - For example, both can form two sigma bonds with substituents. 7. **Bond Angles**: - The bond angles in singlet and triplet carbenes differ due to their different hybridization states. Therefore, they do not share this property. ### Conclusion: From the analysis, we conclude that the only property that singlet and triplet carbenes share is the **number of sigma bonds**. ### Final Answer: **Singlet and triplet carbenes are the same in the number of sigma bonds.**

To solve the question regarding the similarities between singlet and triplet carbenes, we will analyze the properties of both types of carbenes step by step. ### Step-by-Step Solution: 1. **Understanding Carbenes**: - Carbenes are neutral species containing a carbon atom with only six valence electrons, resulting in a divalent state. They can exist in two forms: singlet and triplet. 2. **Singlet Carbene**: ...
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Carbene intermediates are produced by the photolysis of diazomethane (CH_2N_2) or ketene (CH_2 = C = O) . They are also produced by the reaction of CHX_3 with base or by Simmons-Smith reaction. There are two types of carbenes, singlet and triplet. They are so called due to their spin state. Spin state of carbene is determined by using the formula : where S is the sum of all electron spin numbers.

Carbene intermediates are produced by the photolysis of diazomethane (CH_2N_2) or kenene (CH_2 = C = O) . They are also produced by the reaction of CHX_3 with base or by Simmons-Smith reaction. There are two types of carbenes, singlet and triplet. They are so called due to their spin state. Which carbene is produced in the following reactions ? .

Carbene intermediates are produced by the photolysis of diazomethane (CH_2N_2) or kenene (CH_2 = C = O) . They are also produced by the reaction of CHX_3 with base or by Simmons-Smith reaction. There are two types of carbenes, singlet and triplet. They are so called due to their spin state. In which reaction, the insertion of methylene increases potential energy ?

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