Five isomeric p-subsituted aromatic compounds (A) to (E ) with molecular formula `C_(8)H_(8)O_(2)` are given for identifyication. Based on the following observition, give the strucctures of the compounds.
i. Both (A) and (B) form a silver mirror with Tollens reagent, (B) also gives a positive test with neutral `FeCl_(3)` solution.
ii. (C ) gives positive iodoform test.
iii. (D) is readily extracted in aqueous `NaHCO_(3)` solution.
iv. (E ) on acid hydrolysis gives 1,4-dihydroxy benzene. Compound (E ) is:

Options

A.
B.
C.
D.

Explanation

To identify the structures of the five isomeric p-substituted aromatic compounds (A) to (E) with the molecular formula C8H8O2, we will analyze the observations provided step by step.

### Step 1: Analyze the information for Compound E
The only observation provided for compound E is that it gives 1,4-dihydroxybenzene upon acid hydrolysis. This indicates that compound E must have a structure that, when hydrolyzed, results in the formation of 1,4-dihydroxybenzene.

### Step 2: Determine the structure of Compound E
1,4-Dihydroxybenzene (also known as p-hydroquinone) has hydroxyl groups at the 1 and 4 positions on the benzene ring. Therefore, compound E must have a substituent that, when hydrolyzed, can yield this product.

### Step 3: Identify possible structures for Compound E
To yield 1,4-dihydroxybenzene, compound E could be an ether or an alkene that, upon hydrolysis, can rearrange or break down to form the desired product.

Given that:
- A, C, and D already have a hydroxyl group at the para position, they cannot be the source of the additional hydroxyl group after hydrolysis.
- Aldehydes and ketones do not yield 1,4-dihydroxybenzene upon hydrolysis, as they would remain as carbonyl compounds.

### Step 4: Conclusion for Compound E
The most likely candidate for compound E is an alkene or an ether that can yield 1,4-dihydroxybenzene upon hydrolysis.

The structure of compound E can be proposed as:
- An alkene with a structure like p-ethoxybenzene (C6H4(OCH2CH3)) or similar, which can yield 1,4-dihydroxybenzene upon acid hydrolysis.

### Final Structure of Compound E
Thus, the structure of compound E is:
- **p-Ethoxybenzene (C6H4(OCH2CH3))**