Home
Class 12
CHEMISTRY
Which of the statements are about the fo...

Which of the statements are about the following reaction ?

A

Ketones are more reactive than RCOCl, therefore ketones further react with RMgX to give `3^(@)` alcohols.

B

`(C-Mg)` bond is more ionic than `(C-Cu)` or `(C-Cd)` bond.

C

Nucleophile `R^(overset(..)(Θ))` from Grignard reagent is more reactive and the reaction of RMgX with RCOCl is a nucleophilic addition reaction.

D

Cu or Cd forms complex with Cl of RCOCl, `[R-overset(delta+)underset(O)underset(||)C...Cl...overset(delta-)CdR_(2)]`, similar to acylium-like ion with greater `(delta+)` charge on C, which bonds even with the weakly nucleophilic R of `R_(2)Cd` or `R_(2)CuLi`.

Text Solution

Verified by Experts

The correct Answer is:
A, B, C, D
Promotional Banner

Topper's Solved these Questions

  • ALIPHATIC AND AROMATIC ALDEHYDES AND KETONES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Single Correct|71 Videos
  • ALIPHATIC AND AROMATIC ALDEHYDES AND KETONES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Assertion-Reasoning|6 Videos
  • ALIPHATIC AND AROMATIC ALDEHYDES AND KETONES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Linked Comprehension|59 Videos
  • ALCOHOL,PHENOL AND ETHERS

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Analytical And Descriptive|15 Videos
  • APPENDIX INORGANIC VOLUME 2

    CENGAGE CHEMISTRY ENGLISH|Exercise Short Answer Type|179 Videos

Similar Questions

Explore conceptually related problems

Which of the statements are correct about the following reactions ? MeCHO+[Ag(NH_(3))_(2)]^(o+)+overset(Θ)(OH)+ rarr MeCOO^(Θ)+Ag

Which statement is correct about the following reactions ? .

Which statement is correct about the following reactions ? .

Which statement is correct about the following reactions ? .

In elimination reaction, the major product is either Saytzeff (more-substituted alkene) or Hofmann product (less-substituted alkene) depending on the nature of the substrate and the nature of the base. Which statement is correct about the following reactions ?

Which of the following statements about the following reaction is // are Wrong? 2Cu_(2)O(s)+Cu_(2)S(s)rarr6Cu(s)+5O_(2)(g)

What statement is correct about the following reaction

Which of the following statements about the following reaction is // are not correct? Cr_(2)O_(7)^(2-)+3H_(2)O_(2)+8H^(o+)to2Cr^(3+)+7H_(2)O+3O_(2)

Which of the following statements about the following reaction is // are not correct? Cr_(2)O_(7)^(2-)+3H_(2)O_(2)+8H^(o+)to2Cr^(3+)+7H_(2)O+3O_(2)

CENGAGE CHEMISTRY ENGLISH-ALIPHATIC AND AROMATIC ALDEHYDES AND KETONES-Exercises Multiple Correct
  1. Which of the following statements are correct about the following reac...

    Text Solution

    |

  2. Which of the following reactions would give propanal ?

    Text Solution

    |

  3. Which of the statements are about the following reaction ?

    Text Solution

    |

  4. Which of the following would undergo Aldol condensation ?

    Text Solution

    |

  5. Which of the statements are correct about the internal or intramolecul...

    Text Solution

    |

  6. Which of the methods are better in the synthesis of the following comp...

    Text Solution

    |

  7. Which of the following are correct reactions ?

    Text Solution

    |

  8. Which of the following are crossed aldol products in the given reactio...

    Text Solution

    |

  9. Which of the statements are correct about the reaction ? (A) overs...

    Text Solution

    |

  10. Which of the following statements are correct about the reaction given...

    Text Solution

    |

  11. Which of the following are correct reactions ?

    Text Solution

    |

  12. Which of the following statements are correct about the bisulphite add...

    Text Solution

    |

  13. Which of the statements are correct about the following reactions ? ...

    Text Solution

    |

  14. Which of the following are Perkin reactions ?

    Text Solution

    |

  15. Which of the following are correct reactions ?

    Text Solution

    |

  16. Which of the following statements are true about the benzoin reaction ...

    Text Solution

    |

  17. Give a reaction where Lead iodide is formed as one of the product.

    Text Solution

    |

  18. Among the following, the least and the best H^(Θ) ion donor, respectiv...

    Text Solution

    |

  19. Among the following, the best and the least H^(Θ) ion donor, respectiv...

    Text Solution

    |

  20. Among the following, the least and the best H^(Θ) ion donor, respectiv...

    Text Solution

    |