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Which of the statements are correct abou...

Which of the statements are correct about the following reactions ?
`MeCHO+[Ag(NH_(3))_(2)]^(o+)+overset(Θ)(OH)+ rarr MeCOO^(Θ)+Ag`

A

The equivalent weight of `MeCHO` is 22.

B

Three moles of `overset(Θ)(OH)` are required in the above reaction.

C

`MeCHO` is an oxidising agent.

D

Reduction of `[Ag(NH_(3))_(2)]^(o+)` occurs.

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the given reaction and determine which statements are correct, we can break down the process step by step. ### Step 1: Identify the Reaction The reaction provided is: \[ \text{MeCHO} + [\text{Ag(NH}_3)_2]^+ + \text{OH}^- \rightarrow \text{MeCOO}^- + \text{Ag} \] Here, MeCHO represents an aldehyde (specifically, methyl aldehyde or formaldehyde), and [Ag(NH3)2]+ is a complex of silver that acts as an oxidizing agent. ### Step 2: Determine Oxidation and Reduction - **Oxidation**: The aldehyde (MeCHO) is oxidized to a carboxylate ion (MeCOO^-). - **Reduction**: The silver ion (Ag^+) is reduced to metallic silver (Ag). ### Step 3: Balance the Reaction 1. **Balancing Oxygen**: - The aldehyde has one oxygen, and the carboxylate has two oxygens. To balance the oxygen, we can add one water molecule (H2O) on the reactant side: \[ \text{MeCHO} + [\text{Ag(NH}_3)_2]^+ + \text{OH}^- + \text{H}_2O \rightarrow \text{MeCOO}^- + \text{Ag} \] 2. **Balancing Hydrogen**: - In basic medium, we need to add hydroxide ions (OH^-) to balance the hydrogen atoms. For every water molecule added, we add the same number of hydroxide ions to the opposite side. 3. **Balancing Charge**: - The charges must also be balanced. The left side has a total charge of +1 (from [Ag(NH3)2]+) and the right side has -1 (from MeCOO^-). We can add two electrons (2e^-) to the right side to balance the charges. ### Step 4: Identify the Reducing and Oxidizing Agents - The substance that gets oxidized (MeCHO) acts as a **reducing agent**. - The substance that gets reduced ([Ag(NH3)2]+) acts as an **oxidizing agent**. ### Step 5: Evaluate the Statements 1. **Statement A**: The equivalent weight of ethanol is 22. - This is correct as the equivalent weight is calculated based on the molecular weight divided by the number of electrons transferred. 2. **Statement B**: The oxidation of MeCHO occurs. - This is correct as MeCHO is oxidized to MeCOO^-. 3. **Statement C**: Ethanol acts as an oxidizing agent. - This is incorrect because ethanol (MeCHO) is being oxidized, thus it acts as a reducing agent. 4. **Statement D**: The reduction of the silver complex occurs. - This is correct as silver is reduced from Ag^+ to Ag. ### Conclusion The correct statements are A, B, and D.

To analyze the given reaction and determine which statements are correct, we can break down the process step by step. ### Step 1: Identify the Reaction The reaction provided is: \[ \text{MeCHO} + [\text{Ag(NH}_3)_2]^+ + \text{OH}^- \rightarrow \text{MeCOO}^- + \text{Ag} \] Here, MeCHO represents an aldehyde (specifically, methyl aldehyde or formaldehyde), and [Ag(NH3)2]+ is a complex of silver that acts as an oxidizing agent. ...
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