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The most suitable reagent for the conver...

The most suitable reagent for the conversion of
Propanol to Propanal is
a. KMnO4
b.K2Cr2O7
c.CrO3
d. PCC

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The correct Answer is:
To convert propanol (a primary alcohol) to propanal (an aldehyde), we need to choose the most suitable reagent from the given options. Let's analyze each option step by step. ### Step 1: Identify the structure of propanol and propanal - Propanol (C3H8O) is a primary alcohol with the structure CH3-CH2-CH2OH. - Propanal (C3H6O) is an aldehyde with the structure CH3-CH2-CHO. ### Step 2: Understand the oxidation process - The conversion of a primary alcohol to an aldehyde involves oxidation. - A suitable oxidizing agent should be able to oxidize propanol to propanal without further oxidizing it to a carboxylic acid. ### Step 3: Evaluate the reagents 1. **KMnO4 (Potassium permanganate)**: - This is a strong oxidizing agent. It can oxidize primary alcohols to carboxylic acids. Therefore, it would convert propanol to propanoic acid instead of stopping at propanal. 2. **K2Cr2O7 (Potassium dichromate)**: - This is also a strong oxidizing agent. Similar to KMnO4, it would oxidize propanol to propanoic acid, not stopping at the aldehyde stage. 3. **CrO3 (Chromic acid)**: - This is another strong oxidizing agent that would oxidize propanol to propanoic acid, bypassing the aldehyde stage. 4. **PCC (Pyridinium chlorochromate)**: - This is a milder oxidizing agent specifically designed to oxidize primary alcohols to aldehydes without further oxidation to carboxylic acids. It effectively stops the reaction at the aldehyde stage. ### Step 4: Conclusion - Based on the analysis, the most suitable reagent for the conversion of propanol to propanal is **PCC (Pyridinium chlorochromate)**. ### Final Answer: **d. PCC** ---

To convert propanol (a primary alcohol) to propanal (an aldehyde), we need to choose the most suitable reagent from the given options. Let's analyze each option step by step. ### Step 1: Identify the structure of propanol and propanal - Propanol (C3H8O) is a primary alcohol with the structure CH3-CH2-CH2OH. - Propanal (C3H6O) is an aldehyde with the structure CH3-CH2-CHO. ### Step 2: Understand the oxidation process - The conversion of a primary alcohol to an aldehyde involves oxidation. ...
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