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CH-=CH overset(H(g)SO(4))underset(H(2)SO...

`CH-=CH overset(H_(g)SO_(4))underset(H_(2)SO_(4))rarr (X) overset(LiAIH_(4))rarr (Y) overset(P_(4)//Br_(2))rarr (Z)`
In this sequence of reaction, the (Z) is:

A

Ethylene bromide

B

Ethanol

C

Ethyl bromide

D

Ethylidene bromide

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The correct Answer is:
To solve the given reaction sequence step by step, let's analyze each reaction carefully: ### Step 1: Reaction of Alkyne with H₂SO₄ The starting compound is an alkyne, represented as CH≡CH (ethyne or acetylene). When this alkyne reacts with sulfuric acid (H₂SO₄) in the presence of mercury(II) sulfate (HgSO₄), it undergoes hydration. The reaction proceeds as follows: - The alkyne reacts with H₂SO₄ to form an intermediate vinyl alcohol (enol), which is CH₂=CHOH (vinyl alcohol). - This vinyl alcohol then undergoes tautomerization to form an aldehyde. In this case, the aldehyde formed is acetaldehyde (ethanal), represented as CH₃CHO. Thus, the product of this step (X) is: \[ X = CH₃CHO \] ### Step 2: Reduction with Lithium Aluminum Hydride (LiAlH₄) The next step involves the reduction of the aldehyde (X) using lithium aluminum hydride (LiAlH₄). The reaction is as follows: - LiAlH₄ is a strong reducing agent that reduces aldehydes to primary alcohols. - Therefore, the acetaldehyde (CH₃CHO) will be reduced to ethanol (CH₃CH₂OH). Thus, the product of this step (Y) is: \[ Y = CH₃CH₂OH \] ### Step 3: Reaction with Phosphorus and Bromine (P₄/Br₂) In the final step, ethanol (Y) is reacted with phosphorus (P₄) and bromine (Br₂). This reaction is known as the Hell-Volhard-Zelinsky (HVZ) reaction. The reaction proceeds as follows: - Phosphorus reacts with bromine to form phosphorus tribromide (PBr₃). - The hydroxyl group (-OH) of ethanol reacts with PBr₃, leading to the formation of an intermediate that ultimately results in the substitution of the hydroxyl group with a bromine atom. As a result, we obtain bromoethane (ethyl bromide), represented as CH₃CH₂Br. Thus, the final product (Z) is: \[ Z = CH₃CH₂Br \] ### Final Answer The compound Z is bromoethane (ethyl bromide).

To solve the given reaction sequence step by step, let's analyze each reaction carefully: ### Step 1: Reaction of Alkyne with H₂SO₄ The starting compound is an alkyne, represented as CH≡CH (ethyne or acetylene). When this alkyne reacts with sulfuric acid (H₂SO₄) in the presence of mercury(II) sulfate (HgSO₄), it undergoes hydration. The reaction proceeds as follows: - The alkyne reacts with H₂SO₄ to form an intermediate vinyl alcohol (enol), which is CH₂=CHOH (vinyl alcohol). - This vinyl alcohol then undergoes tautomerization to form an aldehyde. In this case, the aldehyde formed is acetaldehyde (ethanal), represented as CH₃CHO. ...
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