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Ethylidene chloride is hydrolysed with a...

Ethylidene chloride is hydrolysed with aqueous NaOH. The product formed is:

A

Ethanol

B

Ethanal

C

Ethanone

D

Ethane

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The correct Answer is:
To solve the problem of what product is formed when ethylidene chloride is hydrolyzed with aqueous NaOH, we can follow these steps: ### Step 1: Identify the Structure of Ethylidene Chloride Ethylidene chloride is a compound with the formula CH3CHCl2. It consists of an ethyl group (CH3CH) attached to two chlorine atoms (Cl). ### Step 2: Understand the Hydrolysis Reaction Hydrolysis in this context involves the reaction of ethylidene chloride with aqueous sodium hydroxide (NaOH). In this reaction, the hydroxide ion (OH-) acts as a nucleophile. ### Step 3: Nucleophilic Substitution The hydroxide ion will attack the carbon atom that is bonded to the chlorine atoms. This leads to a nucleophilic substitution reaction where the chlorine atoms are replaced by hydroxyl groups. ### Step 4: Formation of an Intermediate When the hydroxide ion attacks, we form an intermediate compound. The reaction can be represented as: \[ CH3CHCl2 + 2 OH^- \rightarrow CH3C(OH)(OH) \] This intermediate has two hydroxyl groups attached to the carbon. ### Step 5: Elimination of Water The intermediate is unstable due to the presence of two hydroxyl groups on the same carbon atom. To stabilize, it undergoes dehydration (loss of water) to form a carbonyl compound. The reaction can be represented as: \[ CH3C(OH)(OH) \rightarrow CH3C=O + H2O \] This results in the formation of ethanal (acetaldehyde), which has the structure CH3CHO. ### Step 6: Conclusion The final product of the hydrolysis of ethylidene chloride with aqueous NaOH is ethanal (acetaldehyde). ### Final Answer The product formed is **ethanal (acetaldehyde)**. ---

To solve the problem of what product is formed when ethylidene chloride is hydrolyzed with aqueous NaOH, we can follow these steps: ### Step 1: Identify the Structure of Ethylidene Chloride Ethylidene chloride is a compound with the formula CH3CHCl2. It consists of an ethyl group (CH3CH) attached to two chlorine atoms (Cl). ### Step 2: Understand the Hydrolysis Reaction Hydrolysis in this context involves the reaction of ethylidene chloride with aqueous sodium hydroxide (NaOH). In this reaction, the hydroxide ion (OH-) acts as a nucleophile. ...
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