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When diethyl cadmium [(C(2)H(5))(2)Cd] i...

When diethyl cadmium `[(C_(2)H_(5))_(2)Cd]` is treated with acetyl chloride `[CH_(3)COCl]`, the main product likely to be:

A

Acetone

B

Methyl ethyl ketone

C

Diethyl ketone

D

Acetaldehyde

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The correct Answer is:
To solve the question regarding the reaction of diethyl cadmium with acetyl chloride, we can follow these steps: ### Step 1: Identify the Reactants We have diethyl cadmium, which is represented as \[(C_2H_5)_2Cd\], and acetyl chloride, represented as \[CH_3COCl\]. ### Step 2: Understand the Reaction Mechanism Diethyl cadmium acts as a nucleophile due to the presence of the alkyl groups. In this case, the ethyl groups (\[C_2H_5\]) will attack the carbonyl carbon of acetyl chloride. The carbonyl carbon in acetyl chloride is electrophilic because of the presence of the electronegative chlorine atom. ### Step 3: Nucleophilic Attack When the nucleophile (ethyl group from diethyl cadmium) attacks the carbonyl carbon of acetyl chloride, a tetrahedral intermediate is formed. This intermediate has the structure \[CH_3C(OH)(C_2H_5)Cl\]. ### Step 4: Elimination of Chlorine In the next step, the chlorine atom (which is a good leaving group) will leave, resulting in the formation of a ketone. The oxygen will carry a negative charge, which will stabilize the structure. ### Step 5: Final Product Formation After the elimination of chlorine, the resulting product will be \[CH_3C(=O)C_2H_5\], which is methyl ethyl ketone (also known as 3-pentanone). ### Conclusion The main product formed when diethyl cadmium is treated with acetyl chloride is methyl ethyl ketone. ### Final Answer The correct answer is **methyl ethyl ketone**. ---

To solve the question regarding the reaction of diethyl cadmium with acetyl chloride, we can follow these steps: ### Step 1: Identify the Reactants We have diethyl cadmium, which is represented as \[(C_2H_5)_2Cd\], and acetyl chloride, represented as \[CH_3COCl\]. ### Step 2: Understand the Reaction Mechanism Diethyl cadmium acts as a nucleophile due to the presence of the alkyl groups. In this case, the ethyl groups (\[C_2H_5\]) will attack the carbonyl carbon of acetyl chloride. The carbonyl carbon in acetyl chloride is electrophilic because of the presence of the electronegative chlorine atom. ...
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CENGAGE CHEMISTRY ENGLISH-ALIPHATIC AND AROMATIC ALDEHYDES AND KETONES-Exercises Single Correct
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  2. 2-Propanone (acetone) can be obtained by Wacker's process starting wit...

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  9. A compound has molecular formula C(6)H(12)O. It does not reduce Tollen...

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  12. On treatment of acetone with dilute Ba(OH)(2), the product formed is:

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  13. Formalin is:

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  14. Which of the following is paraldehyde ?

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  15. The product formed by the reaction of acetaldehyde with excess of etha...

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  19. When actaldehyde is treated with hydroxylamine, the medium should be:

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  20. In order to prepare acetone from acetyl chloride in one step, which of...

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