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The following reaction is an example of:...

The following reaction is an example of:
`RCHOHR'+CH_(3)COCH_(3) overset("A1-tert butoxide")underset(((CH_(3))_(3) C-O)_(3)A1)rarr RCOR'+CH_(3)CHOHCH_(3)`

A

Oppenauer oxidation

B

Etard oxidation

C

Pinacol reduction

D

Beta oxidation

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AI Generated Solution

The correct Answer is:
To solve the given question, we need to analyze the reaction provided and identify the type of reaction it represents. The reaction is as follows: \[ RCHO + R'CHOH + CH_3COCH_3 \overset{\text{A1-tert butoxide}}{\longrightarrow} RCOR' + CH_3CHOHCH_3 \] ### Step-by-Step Solution: 1. **Identify the Reactants and Products:** - The reactants include an aldehyde (RCHO), an alcohol (R'CHOH), and acetone (CH₃COCH₃). - The products are a ketone (RCOR') and another alcohol (CH₃CHOHCH₃). 2. **Recognize the Role of the Reagent:** - The reagent used is aluminum tert-butoxide (A1-tert butoxide), which is known to facilitate certain types of oxidation reactions. 3. **Determine the Type of Alcohol:** - The alcohol (R'CHOH) is a secondary alcohol, as it is attached to two carbon atoms. 4. **Analyze the Reaction Type:** - The reaction involves the oxidation of a secondary alcohol to form a ketone. This is characteristic of an open-air oxidation process, where secondary alcohols are oxidized to ketones in the presence of an oxidizing agent. 5. **Consider Other Options:** - **Etard Oxidation:** This is used for oxidizing aromatic methyl groups to aldehydes, which does not apply here. - **Pinacol Oxidation:** This involves the reaction of aldehydes and ketones with magnesium and mercury, which is not present in this reaction. - **Beta Oxidation:** This is related to the oxidation of fatty acids and does not apply to the given reaction. 6. **Conclusion:** - Since the reaction involves the oxidation of a secondary alcohol to a ketone using aluminum tert-butoxide, it is classified as **open-air oxidation**. ### Final Answer: The following reaction is an example of **open-air oxidation**. ---
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