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Name the following reaction. PhCHO+CH(...

Name the following reaction.
`PhCHO+CH_(2)(COOEt)_(2)overset((i) "Pyridine")underset({:((ii)H_(2)O),((iii) Delta","-CO_(2)):})toPh-CH-=CHCOOH`

A

Perkin reaction

B

Aldol condensation

C

Claisen reaction

D

Knoevenagel

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The correct Answer is:
To name the reaction given in the question, we will analyze the components and the conditions under which the reaction occurs. ### Step-by-Step Solution: 1. **Identify the Reactants**: The reactants in the reaction are benzaldehyde (PhCHO) and diethyl malonate (CH₂(COOEt)₂). Benzaldehyde is an aromatic aldehyde, and diethyl malonate contains an active methylene group. 2. **Identify the Conditions**: The reaction occurs in the presence of pyridine, which acts as a weak base, and water is also involved in the reaction. The reaction is followed by heating (indicated by Δ) and the release of carbon dioxide (CO₂). 3. **Analyze the Reaction Type**: - The reaction involves an aromatic aldehyde (benzaldehyde) and an ester (diethyl malonate). - The presence of an active methylene group (the methylene group between two carbonyls in diethyl malonate) is crucial for the reaction to proceed. - The reaction does not involve any alpha hydrogen from the benzaldehyde since it does not have any. 4. **Determine the Name of the Reaction**: - This reaction fits the criteria of the **Noyori Reaction** (also known as the Noyori Aldol Reaction or Noyori Condensation). In the Noyori reaction, an aldehyde or ketone with no alpha hydrogen reacts with a compound containing an active methylene group in the presence of a weak base to form an unsaturated carboxylic acid. 5. **Final Product**: The product formed is an unsaturated carboxylic acid (Ph-CH=CHCOOH), confirming that the reaction is indeed a condensation reaction leading to the formation of an unsaturated acid. ### Conclusion: The name of the reaction is the **Noyori Reaction**. ---
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