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A compound has molecular formula C(6)H(1...

A compound has molecular formula `C_(6)H_(12)O`. It does not reduce Tollens or Fehling's reagent, but gives a crystalline derivative with 2,4-dinitro-phenyl hydrazine. With alkali and `I_(2)`, it gives yellow solid with a medicinal odour. Clemmensen reduction converts it to 2-methylpentane. The structure formula of the compound is most likely to be:

A

`CH_(3)-COCH_(2)-CH-(CH_(3))_(2)`

B

`CH_(3)-CH_(2)-CO-CH-(CH_(3))_(2)`

C

`CH_(3)CH_(2)CH_(2)-CO-CH_(2)CH_(3)`

D

`(CH_(3))_(2)-CH-CO-CH-(CH_(3))_(2)`

Text Solution

Verified by Experts

The correct Answer is:
A

Proceeds reverse from the Clemmensen reduction.
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