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underset((A))(MeCH(2)COOH)underset(under...

`underset((A))(MeCH_(2)COOH)underset(underset((iii)Ag_(2)O //Pt)((ii)CH_(2)N_(2)))overset((i)SOCI)rarr(B)overset(H_(2)O)rarr(C)`
Which of the following statements are correct about the given reaction.

A

The product `(B)` and `(C )`, respectively, are `MeCH=C=O` and `MeCH_2 COOMe`.

B

The products `(B)` and `( C)`, respectively, are : `MeCH_2 CH=C=O` and `MeCH_2 CH_2 COOH`.

C

The reaction is known as Wolff rearrangement reaction.

D

The reaction is known as rearrangement reaction.

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The correct Answer is:
To analyze the reaction sequence and determine the correct statements about the given reaction, we will break down the steps involved in the transformation of propanoic acid (MeCH₂COOH) to the final product (butanoic acid). ### Step-by-Step Solution: 1. **Reaction of Propanoic Acid with SOCl2**: - When propanoic acid reacts with thionyl chloride (SOCl2), the hydroxyl (-OH) group of the carboxylic acid is replaced by a chlorine atom (-Cl). This forms an acid chloride. - **Product A**: The product of this reaction is propanoyl chloride (MeCH₂C(O)Cl). 2. **Reaction with CH2N2 and Silver Oxide (Ag2O) under Platinum (Pt)**: - The next step involves the reaction of the acid chloride with diazomethane (CH2N2) in the presence of silver oxide and platinum. This reaction leads to the formation of a free radical. - The acid chloride undergoes a rearrangement where the ethyl group from the diazomethane attacks the carbonyl carbon, resulting in a new structure. - **Product B**: The product formed here is a compound with a carbonyl group (C=O) and an ethyl group (C2H5) attached to the carbon that was part of the carbonyl. 3. **Hydrolysis of Product B**: - The final step involves hydrolysis, where water is added to Product B. During hydrolysis, the carbonyl bond is broken, and an -OH group is added to one carbon while a hydrogen atom is added to the adjacent carbon. - **Product C**: The final product of this hydrolysis is butanoic acid (C4H8O2), which is a four-carbon carboxylic acid. ### Summary of Products: - **Product A**: Propanoyl chloride (MeCH₂C(O)Cl) - **Product B**: A compound with a carbonyl and ethyl group (C=O with C2H5) - **Product C**: Butanoic acid (C4H8O2) ### Evaluation of Statements: 1. **Statement A**: Incorrect - Product B is not correctly identified, and Product C is butanoic acid. 2. **Statement B**: Correct - Product B has the correct structure with C=O and C2H5. 3. **Statement C**: Correct - Product C is butanoic acid, which has four carbons. 4. **Statement D**: Incorrect - The reaction is a rearrangement, not a Wolf rearrangement. ### Correct Statements: - The correct statements about the reaction are **B** and **C**.
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