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Alkyl isocyanides (Roverset(o+)(N)-=over...

Alkyl isocyanides `(Roverset(o+)(N)-=overset(ɵ)(C ))` are reduced to `2^(@)` amines `(R-NH-CH_(3))` with:

A

a.`LAH`

B

b.`NaBH_(4)`

C

c.`HI+P`

D

d.`H_(2)+Pt`

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The correct Answer is:
To solve the question regarding the reduction of alkyl isocyanides to secondary amines, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Structure of Alkyl Isocyanides**: - Alkyl isocyanides have the general formula `R-N≡C`, where `R` is an alkyl group. The isocyanide functional group consists of a nitrogen atom triple-bonded to a carbon atom. 2. **Understand the Reduction Process**: - Reduction is a chemical reaction that involves the gain of electrons or a decrease in oxidation state. In this case, we are looking to reduce the isocyanide to a secondary amine. 3. **Recognize the Product**: - The product of the reduction of an alkyl isocyanide is a secondary amine, which has the general formula `R-NH-CH3` (where `R` is the alkyl group and `CH3` represents a methyl group). 4. **Identify the Reducing Agent**: - The reduction of alkyl isocyanides to secondary amines can be achieved using hydrogen gas (H2) in the presence of a catalyst. Common catalysts for this type of reaction include platinum (Pt) or palladium (Pd). 5. **Write the Reaction**: - The general reaction can be represented as: \[ R-N≡C + H_2 \xrightarrow{Pt} R-NH-CH_3 \] - Here, the alkyl isocyanide reacts with hydrogen gas in the presence of platinum to yield the corresponding secondary amine. 6. **Conclusion**: - Therefore, the correct answer to the question is that alkyl isocyanides are reduced to secondary amines with hydrogen and platinum. ### Final Answer: Alkyl isocyanides are reduced to secondary amines with hydrogen and platinum. ---
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Monomer of [NH-overset(O)overset(||)C-NH-CH_(2)]n is:

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Which H atom in the following ester is most acidic ? overset(1)(CH_(3))-overset(2)(CH_(2))-overset(O)overset(||)(C)-overset(3)(CH_(2))-overset(O)overset(||)(C)-O-overset(4)(CH_(2))overset(5)(CH_(3))

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CENGAGE CHEMISTRY ENGLISH-REDUCTION AND OXIDATION REACTION OF ORGANIC COMPOUNDS-Exercise (Multiple Correct)
  1. Which of the following reactions is//are correct?

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  2. Which statement(s) is/are wrong?

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  3. Which of the following reaction(s) is/are correct?

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  4. Which of the following reaction(s) is/are wrong?

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  5. Which of the following reactions is/are wrong?

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  6. Which of the following unbalanced reactions is/are correct?

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  7. Which of the following methods is/are correct for the synthesis of ben...

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  8. Which of the following reaction is/are correct?

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  9. Which of the following methods is/are correct for the synthesis of

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  10. Which of the following on oxidation with alkaline KMnO(4) follwed by a...

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  11. Which of the following methods can be used to prepare propanoic acid?

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  12. Which of the following statements is/are correct about formic acid?

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  13. Which of the following can reduce Benedict's solution?

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  14. Benzoic acid and carbolic acid can be distiguished by:

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  15. Which of the following compounds will not give haloform reaction?

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  16. Which of the following compounds do(es) not react with H(2)+Pd+C?

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  17. Which of the following compounds reacts with NaCNBH(3)?

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  18. Acetonitrile (Meoverset(o+)(N)-=overset(ɵ)(C )) on reaction with Cl(2)...

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  19. Alkyl isocyanides (Roverset(o+)(N)-=overset(ɵ)(C )) are reduced to 2^(...

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  20. Methanamide is reduced to methanamine with:

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