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The oxidation state of Fe in brown compl...

The oxidation state of Fe in brown complex `[Fe(H_(2)O)_(5)NO]SO_(4)` is

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To determine the oxidation state of Fe in the complex \([Fe(H_2O)_5NO]SO_4\), we can follow these steps: ### Step-by-Step Solution: 1. **Identify the components of the complex**: The complex consists of five water molecules (H2O), one nitric oxide (NO), and a sulfate ion (SO4). 2. **Determine the oxidation states of the ligands**: - Water (H2O) is a neutral ligand, which means its oxidation state is 0. - Nitric oxide (NO) is a neutral ligand but can also be considered as a positive ligand in some contexts. For this problem, we will consider its oxidation state as +1. - The sulfate ion (SO4) has an oxidation state of -2. 3. **Set up the equation**: Let the oxidation state of Fe be \(x\). The overall charge of the complex \([Fe(H_2O)_5NO]SO_4\) is neutral, which means the sum of the oxidation states must equal 0. The equation can be set up as follows: \[ x + (5 \times 0) + (+1) + (-2) = 0 \] 4. **Simplify the equation**: \[ x + 0 + 1 - 2 = 0 \] \[ x - 1 = 0 \] 5. **Solve for \(x\)**: \[ x = +1 \] 6. **Conclusion**: The oxidation state of Fe in the complex \([Fe(H_2O)_5NO]SO_4\) is +1.
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