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-CONH(2) overset("Reduction")to -CH(2)NH...

`-CONH_(2) overset("Reduction")to -CH_(2)NH_(2)`
In above reaction hybridisation state of carbon changes from

A

`sp to sp^(2)`

B

`sp to sp^(3)`

C

`sp^(2) to sp^(3)`

D

`sp^(2) to sp`

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The correct Answer is:
To solve the problem of determining the change in hybridization state of carbon during the reduction of -CONH2 to -CH2NH2, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Initial Compound**: The initial compound is -CONH2, which is an amide. The carbon in this structure is bonded to a carbonyl group (C=O) and an amine group (NH2). 2. **Determine the Hybridization of Carbon in -CONH2**: - The carbon in -CONH2 is bonded to one oxygen atom via a double bond (C=O) and to one nitrogen atom via a single bond (C-N). - This carbon is also bonded to another hydrogen atom. - Therefore, it has a total of three regions of electron density (one double bond and two single bonds). - According to VSEPR theory, three regions of electron density correspond to **sp² hybridization**. 3. **Identify the Final Compound**: The final compound after reduction is -CH2NH2, which is an amine. 4. **Determine the Hybridization of Carbon in -CH2NH2**: - In -CH2NH2, the carbon is bonded to two hydrogen atoms and one nitrogen atom. - This carbon has four regions of electron density (four single bonds). - Therefore, it corresponds to **sp³ hybridization**. 5. **Conclusion on Hybridization Change**: - The hybridization of carbon changes from **sp²** in -CONH2 to **sp³** in -CH2NH2. - Thus, the change in hybridization state of carbon during the reduction process is from sp² to sp³. ### Final Answer: The hybridization state of carbon changes from **sp² to sp³**. ---
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AAKASH INSTITUTE ENGLISH-AMINES -Assignment Section -A Competition Level Questions
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  10. The correct increasing order is basic strength for the following compo...

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  11. Which of the following is the least basic?

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  12. CH(3)CH(2)NH(2) contains a basic NH(2) group, but CH(3)CONH(2) does no...

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  13. The decreasing order of the basic character of NH(3), CH(3)NH(2), C(2)...

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  14. The one which is the least basic

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  15. Strongest base is

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  16. An amine reacts with C(6)H(5)SO(2)Cl and the product is soluble in alk...

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  17. Which one is most volatile?

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