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The incorrect match is...

The incorrect match is

A

B

C

D

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The correct Answer is:
To determine the incorrect match regarding the aromaticity of the given compounds, we will analyze each option based on the rules of aromaticity and anti-aromaticity. ### Step-by-Step Solution: 1. **Understand the Rules of Aromaticity:** - A compound is aromatic if it satisfies the following criteria: - It is cyclic. - It is planar. - It has a conjugated π electron system. - It follows Huckel's rule: the number of π electrons (denoted as \( n \)) must be of the form \( 4n + 2 \) (where \( n \) is a non-negative integer, e.g., 2, 6, 10, etc.). - A compound is anti-aromatic if it has \( 4n \) π electrons (e.g., 4, 8, 12, etc.). - If a compound does not meet the criteria for aromatic or anti-aromatic, it is classified as non-aromatic. 2. **Evaluate Each Option:** - **Option A:** Count the π electrons. If it has 4 π electrons, it is anti-aromatic. This option is correctly matched. - **Option B:** Analyze the structure. If it has 6 π electrons (2 from double bonds and 4 from other sources), it is aromatic. The presence of a vacant orbital in boron allows it to participate in resonance, stabilizing the compound. Thus, this option is incorrectly matched as aromatic instead of anti-aromatic. - **Option C:** If there are no π electrons, it is non-aromatic. This option is correctly matched. - **Option D:** If there are 6 π electrons (including a negative charge representing 2 electrons), it is aromatic. This option is correctly matched. 3. **Identify the Incorrect Match:** - After evaluating all options, we find that **Option B** is incorrectly matched as it should be classified as aromatic due to the presence of 6 π electrons. ### Final Answer: The incorrect match is **Option B**.
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