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The reaction of CH(3)CH=CH(2) with HOCl ...

The reaction of `CH_(3)CH=CH_(2)` with HOCl will yield

A

2-chloro-1-propanol

B

3-chloro-2-propanol

C

1-chloro-2-propanol

D

1-chloro-1-propanol

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the reaction of propene (CH₃CH=CH₂) with HOCl, we can follow these steps: ### Step 1: Identify the Reactants The reactant is propene, which has the structure CH₃CH=CH₂. The other reactant is HOCl, which consists of a hydroxyl group (OH) and a chlorine atom (Cl). ### Step 2: Understand the Electrophilic Addition Mechanism In the reaction, the double bond in propene acts as a nucleophile and attacks the electrophilic part of HOCl. The oxygen in HOCl is more electronegative, resulting in a partial positive charge on the chlorine atom (Cl) and a partial negative charge on the oxygen (O). ### Step 3: Formation of a Carbocation When the double bond attacks the chlorine, a carbocation is formed. In this case, the more stable secondary carbocation is formed at the second carbon (C2) of propene: - CH₃CH⁺CH₂Cl ### Step 4: Nucleophilic Attack by Hydroxide Ion The hydroxide ion (OH⁻) from HOCl will then attack the carbocation. This results in the formation of a compound where the OH group is attached to the second carbon: - CH₃CHOHCH₂Cl ### Step 5: Naming the Product Now, we need to name the product. The compound has: - A chlorine atom (Cl) on the first carbon (C1) - A hydroxyl group (OH) on the second carbon (C2) Thus, the IUPAC name of the compound is 1-chloro-2-propanol, which can also be referred to as 1-chloro-2-propanol. ### Conclusion The final product of the reaction of propene (CH₃CH=CH₂) with HOCl is 1-chloro-2-propanol. ### Answer The correct option is **1-chloro-2-propanol**. ---
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AAKASH INSTITUTE ENGLISH-HYDROCARBONS-Assignment(Section - A) (Obejctive type question)
  1. The possible compound A is

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  2. Which one of the following cannot be prepared by Wurtz reaction?

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  3. The reaction of CH(3)CH=CH(2) with HOCl will yield

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  4. C(6)H(5)CH(2)CH(2)CH(3) is when oxidised in the presence of alk. KMnO(...

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  5. Toulene overset(K(2)Cr(2)O(7))underset(H(2)SO(4))to Y. Here Y is

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  6. C(6)H(6)+Z overset(Anhy.AlCl(3))to Toluene The compound Z is

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  7. C(6)H(6) overset("Oxidation")underset(V(2)O(5)//Delta)to X. Here, X is

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  8. In kharash effect,reaction follows

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  9. A,B and C can be

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  10. Benzene undergoes substituion reaction more easily than addition becau...

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  11. A mixture of C(2)H(6), C(2)H(4) and C(2)H(2) is bubbled through alkali...

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  12. Ethylene reacts with S(2)Cl(2) to give

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  13. Ph-C-=CH overset(Hg^(+),H^(+)//H(2)O)to A Aditon of H(2)O in the rea...

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  14. Monomer of neoprene is

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  15. Compound A is :

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  16. Compound A is :

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  17. Which of the following is active species in sulphonation of benzene ?

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  18. Which one is o, p-directiong group for electrophliic substitution reac...

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  19. underset((I))("In Chlorobenzene") , underset((II))("2,4-dinitrochlorob...

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  20. CH(3)-CH=CH-CH(2)-CH(3) overset(HI)to underset("major")A Compound A ...

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