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Three atoms A, B and C crystallize in a ...

Three atoms A, B and C crystallize in a cubic solid lattice where A atoms are present at the body centre, B atoms are present at the edge centre as well as at the corners of the cube and C atoms are present at the face centres of the cube. Now if all the atoms are removed from the two 4-fold axis and the one 2-fold axis passing through the cube, then the formula of the compound is

A

`B_7 C_2`

B

A B_2 C_7

C

ABC_2

D

`A_5 C_2`

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The correct Answer is:
To solve the problem, we need to determine the number of atoms of A, B, and C present in the cubic lattice after removing the specified atoms. Let's break it down step by step. ### Step 1: Identify the positions of the atoms - **A atoms** are located at the body center of the cube. - **B atoms** are located at the edge centers and corners of the cube. - **C atoms** are located at the face centers of the cube. ### Step 2: Calculate the number of A atoms - In a cubic unit cell, there is **1 A atom** at the body center. - Since no A atoms are removed from the body center, the total number of A atoms remains **1**. ### Step 3: Calculate the number of B atoms - **B atoms** are located at the edge centers and corners: - There are **12 edges** in a cube, and each edge contributes **1/4** of an atom (since each edge atom is shared by 4 unit cells). \[ \text{Total from edges} = 12 \times \frac{1}{4} = 3 \] - There are **8 corners** in a cube, and each corner contributes **1/8** of an atom (since each corner atom is shared by 8 unit cells). \[ \text{Total from corners} = 8 \times \frac{1}{8} = 1 \] - Therefore, the total number of B atoms before removal is: \[ \text{Total B} = 3 + 1 = 4 \] ### Step 4: Calculate the number of C atoms - **C atoms** are located at the face centers: - There are **6 faces** in a cube, and each face contributes **1/2** of an atom (since each face atom is shared by 2 unit cells). \[ \text{Total C} = 6 \times \frac{1}{2} = 3 \] ### Step 5: Remove atoms from specified axes - **Removing atoms from the two 4-fold axes**: - Each 4-fold axis passes through the face centers. Since there are **2 face centers** along these axes, we remove **2 C atoms**. - **Removing atoms from the one 2-fold axis**: - The 2-fold axis passes through the body center, removing **1 A atom**. ### Step 6: Calculate remaining atoms after removal - Remaining A atoms: \[ \text{Remaining A} = 1 - 1 = 0 \] - Remaining B atoms: - No B atoms are removed, so remaining B atoms are still **4**. - Remaining C atoms: \[ \text{Remaining C} = 3 - 2 = 1 \] ### Step 7: Write the formula of the compound - The remaining atoms can be summarized as: - A: 0 - B: 4 - C: 1 - Therefore, the formula of the compound is: \[ \text{Formula} = B_4C_1 \] ### Final Answer The formula of the compound is \( B_4C \).
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