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CH(3)CHO+CH(3)CH(2)CHOoverset(dil. NaOH)...

`CH_(3)CHO+CH_(3)CH_(2)CHOoverset(dil. NaOH)rarr`
The number of product `(s)` in the above reaction is ( are) ( excluding stereoisomers )

A

1

B

2

C

3

D

4

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The correct Answer is:
To solve the problem of determining the number of products formed in the reaction of CH₃CHO (acetaldehyde) with CH₃CH₂CHO (butanal) in the presence of dilute NaOH, we will follow these steps: ### Step 1: Identify the Reaction Type The reaction between aldehydes in the presence of a base (dilute NaOH) is known as aldol condensation. This reaction can lead to both self-condensation and cross-condensation products. **Hint:** Remember that aldol condensation involves the formation of β-hydroxy aldehydes or ketones, which can further dehydrate to form α,β-unsaturated carbonyl compounds. ### Step 2: Self-Condensation of CH₃CHO First, let's consider the self-condensation of acetaldehyde (CH₃CHO): - Two molecules of CH₃CHO can react. - One molecule acts as a nucleophile and attacks the carbonyl carbon of another molecule, leading to the formation of 3-hydroxybutanal (CH₃CH(OH)CH₂CHO). - This product can then lose a water molecule (dehydration) to form crotonaldehyde (CH₃CH=CHCHO). **Hint:** For self-condensation, look for the formation of a β-hydroxy aldehyde followed by dehydration. ### Step 3: Self-Condensation of CH₃CH₂CHO Next, consider the self-condensation of butanal (CH₃CH₂CHO): - Two molecules of CH₃CH₂CHO can react similarly. - This leads to the formation of 3-hydroxy-2-methylbutanal (CH₃CH(OH)CH₂CH₂CHO). - Upon dehydration, this product forms 3-methylcrotonaldehyde (CH₃C(CH₃)=CHCHO). **Hint:** Self-condensation will yield another β-hydroxy aldehyde that can also undergo dehydration. ### Step 4: Cross-Condensation Products Now, let's consider the cross-condensation products: 1. **Cross product from CH₃CHO and CH₃CH₂CHO:** - One molecule of CH₃CHO can react with one molecule of CH₃CH₂CHO. - This leads to the formation of 3-hydroxy-2-methylbutanal (CH₃C(OH)(CH₂CHO)CH₂CHO). - Upon dehydration, it forms 3-methylcrotonaldehyde (CH₃C(CH₃)=CHCHO). 2. **Another cross product:** - The other cross product can be formed similarly, leading to a different structure but still resulting in a similar dehydrated product. **Hint:** Cross-condensation products can be formed by mixing different aldehydes, leading to unique β-hydroxy products. ### Step 5: Count the Unique Products From the above reactions, we can summarize: - From self-condensation of CH₃CHO: 1 product (crotonaldehyde). - From self-condensation of CH₃CH₂CHO: 1 product (3-methylcrotonaldehyde). - From cross-condensation: 2 unique products (both leading to similar structures). Thus, the total number of unique products, excluding stereoisomers, is **4**. ### Final Answer The total number of products formed in the reaction is **4**.

To solve the problem of determining the number of products formed in the reaction of CH₃CHO (acetaldehyde) with CH₃CH₂CHO (butanal) in the presence of dilute NaOH, we will follow these steps: ### Step 1: Identify the Reaction Type The reaction between aldehydes in the presence of a base (dilute NaOH) is known as aldol condensation. This reaction can lead to both self-condensation and cross-condensation products. **Hint:** Remember that aldol condensation involves the formation of β-hydroxy aldehydes or ketones, which can further dehydrate to form α,β-unsaturated carbonyl compounds. ### Step 2: Self-Condensation of CH₃CHO ...
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RESONANCE ENGLISH-ALDEHYDES, KETONES, CARBOXYLIC ACID-ORGANIC CHEMISTRY(Aldehydes , Ketones, Carboxylic acid)
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