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3CH(3)CHOunderset(298K)overset(H^(o+))ra...

`3CH_(3)CHOunderset(298K)overset(H^(o+))rarrP`
Product P is a pleasant smelling liquid `( B.P. 410K).` . It is used
as a hypnotic. The structure of P is `:`

A

`CH_(3)-CH=CH-CHO`

B

C

`CH_(3)-underset(underset(OH)|)(C)H-CH_(2)-CHO`

D

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AI Generated Solution

The correct Answer is:
To solve the question regarding the reaction of acetaldehyde (CH₃CHO) in the presence of H⁺ at 298 K to form product P, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: We start with three molecules of acetaldehyde (CH₃CHO). 2. **Understand the Reaction Conditions**: The reaction occurs in the presence of H⁺ ions (which can be provided by a strong acid like concentrated H₂SO₄) at a temperature of 298 K. 3. **Recognize the Type of Reaction**: The reaction involves the condensation of acetaldehyde molecules. Under acidic conditions, acetaldehyde can undergo self-condensation to form a cyclic trimer. 4. **Draw the Structure of the Product**: The condensation of three acetaldehyde molecules results in the formation of paraldehyde, which is a cyclic compound. The structure can be represented as: - A six-membered ring with alternating carbon and oxygen atoms. - Each carbon in the ring is bonded to a methyl group (CH₃). 5. **Confirm the Properties of Product P**: - Paraldehyde is a pleasant-smelling liquid with a boiling point of approximately 410 K. - It is known to be used as a hypnotic in medicine. 6. **Final Structure of Product P**: The structure of paraldehyde can be represented as: ``` O / \ CH3 CH | | CH CH3 \ / O ``` This cyclic structure confirms that the product P is paraldehyde. ### Conclusion: The product P formed from the reaction of three molecules of acetaldehyde in the presence of H⁺ at 298 K is paraldehyde, which is a cyclic trimer of acetaldehyde.
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RESONANCE ENGLISH-ALDEHYDES, KETONES, CARBOXYLIC ACID-ORGANIC CHEMISTRY(Aldehydes , Ketones, Carboxylic acid)
  1. CH(3)CHO+CH(3)CH(2)CHOoverset(dil. NaOH)rarr The number of product ...

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  2. The porduct is :

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  3. 3CH(3)CHOunderset(298K)overset(H^(o+))rarrP Product P is a pleasant ...

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  4. If 3- hexanone is reacted with NaBH(4) followed by hydrolysis with D(2...

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  5. Which of the following compounds is most acidic ?

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  6. The treatment of with concentrated KOH gives

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  7. Electrolysis can be used to determine atomic masses. A current of 0.44...

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  8. The compound which would yield 5- Oxo-2-methylhexanal on reductive ozo...

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  9. Which of the following on heating does not form an anhydride ?

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  10. The productP is :

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  11. {:(CH(3)COOH,H-COOCH(3),CH(3)-CONH(2),CH(3)-CH(2)-CH(2)-OH,),((I),(II)...

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  12. Dry distillation of calcium acetate gives :

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  13. Which one of the following reaction is called Rosenmund reaction ?

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  14. How many electrons with l=2 are there in an atom having atomic number ...

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  15. In order to get propane gas which of the following should be subjected...

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  16. Acetic acid reacts separately with the following alcohols. The rate ...

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  17. If the Planck's constant h=6.6×10^(-34) Js, the de Broglie wave length...

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  18. A new carbon-carbon bond formation is possible in:

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  19. Aldehydes and ketones may be distinguished by using

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  20. If the Planck's constant h=6.6×10^(-34) Js, the de Broglie wave length...

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