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If 3- hexanone is reacted with NaBH(4) f...

If `3-` hexanone is reacted with `NaBH_(4)` followed by hydrolysis with `D_(2)O` , the product will be `:`

A

`CH_(3)-CH_(2)-underset(underset(OD)|)(C)H-CH_(2)-CH_(2)-CH_(3)`

B

`CH_(3)-CH_(2)-underset(underset(OD)|)overset(overset(D)|)(C)-CH_(2)-CH_(3)`

C

`CH_(3)-CH_(2)-underset(underset(OH)|)overset(overset(D)|)(C)-CH_(2)-CH_(2)-CH_(3)`

D

`CH_(3)-CH_(2)-underset(underset(OH)|)(C)H-CH_(2)-CH_(2)-CH_(3)`

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The correct Answer is:
To solve the question regarding the reaction of 3-hexanone with sodium borohydride followed by hydrolysis with D2O, we can break it down into a series of steps: ### Step-by-Step Solution: 1. **Identify the Structure of 3-Hexanone**: - 3-Hexanone is a ketone with the molecular formula C6H12O. Its structure can be represented as: ``` CH3-CH2-CO-CH2-CH2-CH3 ``` - The carbonyl (C=O) group is located at the third carbon. 2. **Reaction with Sodium Borohydride (NaBH4)**: - Sodium borohydride is a reducing agent that reduces ketones to alcohols. - When 3-hexanone reacts with NaBH4, the carbonyl group (C=O) is reduced to a hydroxyl group (–OH). - The product after this reduction will be: ``` CH3-CH2-CHOH-CH2-CH2-CH3 ``` - This compound is 3-hexanol. 3. **Hydrolysis with D2O**: - Hydrolysis with D2O involves the exchange of the hydrogen atom in the hydroxyl group (–OH) with deuterium (D). - Therefore, the hydroxyl group in 3-hexanol will be converted to a deuterated hydroxyl group (–OD). - The final product after hydrolysis will be: ``` CH3-CH2-CH(OD)-CH2-CH2-CH3 ``` - This can also be written as: ``` CH3-CH2-CH(OD)-CH2-CH2-CH3 ``` 4. **Final Product**: - The final product of the reaction is 3-hexanol where the hydroxyl group is replaced with deuterium, resulting in: ``` CH3-CH2-CH(OD)-CH2-CH2-CH3 ``` ### Final Answer: The product will be 3-hexanol with deuterium, represented as: ``` CH3-CH2-CH(OD)-CH2-CH2-CH3 ```

To solve the question regarding the reaction of 3-hexanone with sodium borohydride followed by hydrolysis with D2O, we can break it down into a series of steps: ### Step-by-Step Solution: 1. **Identify the Structure of 3-Hexanone**: - 3-Hexanone is a ketone with the molecular formula C6H12O. Its structure can be represented as: ``` CH3-CH2-CO-CH2-CH2-CH3 ...
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RESONANCE ENGLISH-ALDEHYDES, KETONES, CARBOXYLIC ACID-ORGANIC CHEMISTRY(Aldehydes , Ketones, Carboxylic acid)
  1. The porduct is :

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  2. 3CH(3)CHOunderset(298K)overset(H^(o+))rarrP Product P is a pleasant ...

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  3. If 3- hexanone is reacted with NaBH(4) followed by hydrolysis with D(2...

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  4. Which of the following compounds is most acidic ?

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  5. The treatment of with concentrated KOH gives

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  6. Electrolysis can be used to determine atomic masses. A current of 0.44...

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  7. The compound which would yield 5- Oxo-2-methylhexanal on reductive ozo...

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  8. Which of the following on heating does not form an anhydride ?

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  9. The productP is :

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  10. {:(CH(3)COOH,H-COOCH(3),CH(3)-CONH(2),CH(3)-CH(2)-CH(2)-OH,),((I),(II)...

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  11. Dry distillation of calcium acetate gives :

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  12. Which one of the following reaction is called Rosenmund reaction ?

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  13. How many electrons with l=2 are there in an atom having atomic number ...

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  14. In order to get propane gas which of the following should be subjected...

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  15. Acetic acid reacts separately with the following alcohols. The rate ...

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  16. If the Planck's constant h=6.6×10^(-34) Js, the de Broglie wave length...

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  17. A new carbon-carbon bond formation is possible in:

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  18. Aldehydes and ketones may be distinguished by using

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  19. If the Planck's constant h=6.6×10^(-34) Js, the de Broglie wave length...

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  20. If the Planck's constant h=6.6×10^(-34) Js, the de Broglie wave length...

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