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If CH(2)COOH+OH^(-)rarrCH(3)COO^(-)+H(2)...

If `CH_(2)COOH+OH^(-)rarrCH_(3)COO^(-)+H_(2)O+q_(1)`
`H^(+)+OH^(-)rarrH_(2)O+q_(2)`
then the enthalpy change for the equal to

A

`(q_(1)+q_(2))`

B

`(q_(1)-q_(2))`

C

`(q_(2)-q_(1))`

D

`-(q_(1)+q_(2))`

Text Solution

AI Generated Solution

The correct Answer is:
To find the enthalpy change for the reactions given, we will analyze both reactions step by step. ### Step 1: Understand the reactions We have two reactions: 1. \( CH_2COOH + OH^- \rightarrow CH_3COO^- + H_2O + q_1 \) 2. \( H^+ + OH^- \rightarrow H_2O + q_2 \) ### Step 2: Identify the type of reactions - The first reaction involves a weak acid (\( CH_2COOH \)) reacting with a strong base (\( OH^- \)). - The second reaction is a neutralization reaction between a strong acid (\( H^+ \)) and a strong base (\( OH^- \)). ### Step 3: Define the heat of the reactions - \( q_1 \) is the heat evolved in the first reaction (weak acid with strong base). - \( q_2 \) is the heat evolved in the second reaction (strong acid with strong base). ### Step 4: Relate the heats of the reactions The heat of reaction for the first reaction (\( q_1 \)) is less than that of the second reaction (\( q_2 \)), because the first reaction involves the dissociation of a weak acid. ### Step 5: Write the relationship The difference in heat between the two reactions can be expressed as: \[ q_2 - q_1 = \text{Heat of dissociation of the weak acid} \] ### Step 6: Conclusion Thus, the enthalpy change for the reaction involving the weak acid and the strong base can be expressed as: \[ \Delta H = q_2 - q_1 \] ### Final Answer The enthalpy change for the reaction is given by: \[ \Delta H = q_2 - q_1 \] ---

To find the enthalpy change for the reactions given, we will analyze both reactions step by step. ### Step 1: Understand the reactions We have two reactions: 1. \( CH_2COOH + OH^- \rightarrow CH_3COO^- + H_2O + q_1 \) 2. \( H^+ + OH^- \rightarrow H_2O + q_2 \) ### Step 2: Identify the type of reactions ...
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RESONANCE ENGLISH-THERMODYNAMICS-Exercise -1 Part -II Only option correct type
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