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A(s)hArrB(g)+C(g) K(p(1))=36 atm^(2) E...

`A(s)hArrB(g)+C(g) K_(p_(1))=36 atm^(2)`
`E(s)hArrB(g)+D(g) K_(p_(2))=64atm^(2)`
Both solids `A "&" E` were taken in a container of constant volume at a give temperature. Total pressure in the container after equilibrium is

A

`6` atm

B

`5` atn

C

`10` atm

D

`20` atm

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To find the total pressure in the container after equilibrium is reached, we can follow these steps: ### Step 1: Write the equilibrium expressions for both reactions. For the first reaction: \[ A(s) \rightleftharpoons B(g) + C(g) \] The equilibrium constant \( K_{p1} \) is given as: \[ K_{p1} = P_B \cdot P_C = 36 \, \text{atm}^2 \] For the second reaction: \[ E(s) \rightleftharpoons B(g) + D(g) \] The equilibrium constant \( K_{p2} \) is given as: \[ K_{p2} = P_B \cdot P_D = 64 \, \text{atm}^2 \] ### Step 2: Define the pressures of the gases. Let: - \( P_B = P_1 + P_2 \) (where \( P_1 \) is the partial pressure of \( B \) from the first reaction and \( P_2 \) is the partial pressure of \( B \) from the second reaction). ### Step 3: Substitute \( P_B \) in the equilibrium expressions. From the first reaction: \[ K_{p1} = P_B \cdot P_C = (P_1 + P_2) \cdot P_1 = 36 \] From the second reaction: \[ K_{p2} = P_B \cdot P_D = (P_1 + P_2) \cdot P_2 = 64 \] ### Step 4: Rearrange the equations. From the first equation: \[ P_B \cdot P_C = 36 \] \[ P_C = \frac{36}{P_B} \] From the second equation: \[ P_B \cdot P_D = 64 \] \[ P_D = \frac{64}{P_B} \] ### Step 5: Add the pressures. The total pressure \( P_{total} \) in the container is: \[ P_{total} = P_B + P_C + P_D \] Substituting \( P_C \) and \( P_D \): \[ P_{total} = P_B + \frac{36}{P_B} + \frac{64}{P_B} \] \[ P_{total} = P_B + \frac{100}{P_B} \] ### Step 6: Set up the equation using the values of \( K_{p1} \) and \( K_{p2} \). We know: \[ K_{p1} + K_{p2} = 100 \] Thus: \[ P_B^2 = 100 \] Taking the square root: \[ P_B = 10 \] ### Step 7: Calculate the total pressure. Substituting \( P_B \) back into the total pressure equation: \[ P_{total} = 10 + \frac{100}{10} \] \[ P_{total} = 10 + 10 = 20 \, \text{atm} \] ### Final Answer: The total pressure in the container after equilibrium is: \[ \boxed{20 \, \text{atm}} \] ---
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RESONANCE ENGLISH-CHEMICAL EQUILIBRIUM-Exercise-1 (Part-2)
  1. An endothermic reaction is represented by the graph:

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  2. The value of DeltaG^(@) for a reaction in aqueous phase having K(c)=1,...

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  3. The effect of temperature on equilibrium constant is expressed as(T(2)...

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  4. For the reaction CO(g)+H(2)O(g) hArr CO(2)(g)+H(2)(g) at a given t...

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  5. Given the following reaction at equilibrium N(2)(g) + 3H(2)(g)hArr2NH(...

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  6. The equilibrium SO(2)Cl(2)(g) hArr SO(2)(g)+Cl(2)(g) is attained at 25...

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  7. Densities of diamond and graphite are (3.5g)/(mL) and (2.3g)/(mL). C...

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  8. Introduction of inert gas (at the same temperature) will affect the eq...

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  9. The equilibrium SO(2)Cl(2)(g) hArr SO(2)(g)+Cl(2)(g) is attained at 25...

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  10. An equilibrium mixture in a vessel of capacity 100 litre contain 1 "mo...

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  11. For an equilibrium H(2)O(s)hArrH(2)O(l), which of the following statem...

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  12. A reaction in equilibrium is respresnt by the following equation 2A((s...

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  13. For the reaction CO(g)+H(2)O(g) hArr CO(2)(g)+H(2)(g) at a given t...

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  14. The two equilibrium AB hArr A^(+) + B^(-) and AB+B^(-)hArrAB(2)^(-) ar...

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  15. In the preceeding problem, if[A^(+)]"and"[AB(2)^(-)] "are " y " and "...

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  16. The following two reactions: i. PCl(5)(g) hArr PCl(3)(g)+Cl(2)(g) ...

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  17. C(s)+CO(2)(g)hArr2CO(g) K(p)=1atm CaCO(3)(s)hArrCaO(s)+CO(2)(s) K(p)...

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  18. Na(2)SO(4).10H(2)O(s)hArrNa(2)SO(4).5H(2)O(g) K(P)=2.43xx10^(-8) atm^(...

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  19. A(s)hArrB(g)+C(g) K(p(1))=36 atm^(2) E(s)hArrB(g)+D(g) K(p(2))=64atm...

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  20. In a closed container following equilibrium will be attained- A(s)+B...

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