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Para toluidine is treated with HNO(2) at...

Para toluidine is treated with `HNO_(2)` at ice cold condtions and then boiled with water. The final product obtained is:

A

anthranilic acid

B

p-cresol

C

toluic acid

D

phenol

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem of what final product is obtained when para-toluidine is treated with HNO₂ at ice-cold conditions and then boiled with water, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Structure of Para-Toluidine:** Para-toluidine has a benzene ring with an amino group (–NH₂) and a methyl group (–CH₃) at the para position. The structure can be represented as: ``` NH2 | C6H4-CH3 ``` 2. **Reaction with HNO₂ (Diazotization):** When para-toluidine is treated with nitrous acid (HNO₂) at ice-cold conditions, a diazotization reaction occurs. The amino group (–NH₂) is converted into a diazonium ion (–N₂⁺) at the para position: ``` N2⁺ | C6H4-CH3 ``` 3. **Boiling with Water:** The diazonium salt formed is then treated with boiling water. The water will attack the diazonium group, leading to the loss of nitrogen gas (N₂) and the formation of a hydroxyl group (–OH) at the para position: ``` OH | C6H4-CH3 ``` 4. **Final Product:** The final product after the reaction is para-cresol (also known as para-methylphenol), which has the following structure: ``` OH | C6H4-CH3 ``` 5. **Conclusion:** Therefore, the final product obtained from the reaction of para-toluidine with HNO₂ followed by boiling with water is para-cresol. ### Final Answer: The final product obtained is **para-cresol**.
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