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Triethylamine is reacted with a peracid ...

Triethylamine is reacted with a peracid to obtain X. The nitrogen atom in X has formal charge.

A

0

B

`+1`

C

`-1`

D

`+2`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze the reaction of triethylamine with a peracid and determine the formal charge on the nitrogen atom in the resulting product, which we will denote as X. ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactant is triethylamine, which has the structure: \[ (C_2H_5)_3N \] - The peracid can be represented generally as \( RCO_3H \). 2. **Understand the Reaction**: - When triethylamine reacts with a peracid, it forms an amine oxide. The reaction can be represented as: \[ (C_2H_5)_3N + RCO_3H \rightarrow (C_2H_5)_3N^+O^- + RCO_2H \] - In this reaction, the nitrogen atom in triethylamine gets oxidized to form triethylamine oxide. 3. **Draw the Structure of the Product**: - The product, triethylamine oxide, can be depicted as: \[ (C_2H_5)_3N^+O^- \] - Here, the nitrogen atom is bonded to three ethyl groups and has a positive charge due to the addition of the oxygen atom. 4. **Determine the Formal Charge on Nitrogen**: - To calculate the formal charge on the nitrogen atom, we use the formula: \[ \text{Formal Charge} = \text{Valence Electrons} - \text{Non-bonding Electrons} - \frac{1}{2} \text{Bonding Electrons} \] - For nitrogen in triethylamine oxide: - Valence Electrons of Nitrogen = 5 - Non-bonding Electrons = 0 (since it is fully bonded) - Bonding Electrons = 6 (3 bonds with the ethyl groups and 1 bond with oxygen) - Plugging these values into the formula: \[ \text{Formal Charge} = 5 - 0 - \frac{1}{2}(6) = 5 - 3 = +1 \] 5. **Conclusion**: - The formal charge on the nitrogen atom in the product X (triethylamine oxide) is +1. ### Final Answer: The nitrogen atom in product X has a formal charge of +1. ---
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