Home
Class 12
CHEMISTRY
In hexagonal systems of crystals, a freq...

In hexagonal systems of crystals, a frequently encountered arrangement of atoms is described as a hexagonal prism. Here, the top and bottom of the cell are regular hexagons and three atoms are sandwiched in between them. A space-filling model of this structure, called hexagonal close-packed (HCP), is constituted of a sphere on a flat surface surrounded in the same plane by six identical spheres as closely as possible. Three spheres are then placed over the first layer so that they touch each other and represent the second layer. Each one of these three spheres touches three spheres of the bottom layer. Finally, the second layer is covered with a third layer that is identical to the bottom layer in relative position. Assume radius of every sphere to be ‘r’.
The volume of this HCP unit cell is

A

`24sqrt(2) r^(3)`

B

`16sqrt(2) r^(3)`

C

`12sqrt(2) r^(3)`

D

`(64)/(3sqrt(3)) r^(3)`

Text Solution

Verified by Experts

Area of the hexagon = `6 r^(2) sqrt(3)`, height of the hexagon = `4r sqrt((2)/(3))`, volume = `24sqrt(2)r^(3) `
Promotional Banner

Topper's Solved these Questions

  • THE SOLID STATE

    VMC MODULES ENGLISH|Exercise FUNDAMENTAL|50 Videos
  • THE SOLID STATE

    VMC MODULES ENGLISH|Exercise ENABLE|50 Videos
  • THE SOLID STATE

    VMC MODULES ENGLISH|Exercise JEE Main (Archive )|39 Videos
  • SURFACE CHEMISTRY

    VMC MODULES ENGLISH|Exercise PRACTICE EXERCISE|9 Videos
  • THEORY OF SOLUTIONS

    VMC MODULES ENGLISH|Exercise JEE Advanced (Archive)|31 Videos

Similar Questions

Explore conceptually related problems

In hexagonal systems of crystals, a frequently encountered arrangement of atoms is described as a hexagonal prism. Here, the top and bottom of the cell are regular hexagons and three atoms are sandwiched in between them. A space-filling model of this structure, called hexagonal close-packed (HCP), is constituted of a sphere on a flat surface surrounded in the same plane by six identical spheres as closely as possible. Three spheres are then placed over the first layer so that they touch each other and represent the second layer. Each one of these three spheres touches three spheres of the bottom layer. Finally, the second layer is covered with a third layer that is identical to the bottom layer in relative position. Assume radius of every sphere to be ‘r’. The empty space in this HCP unit cell is :

In a hexagonal system system of crystals, a frequently encountered arrangement of atoms is described as a hexagonal prism. Here, the top and bottom of the cell are regular hexagons, and three atoms are sandwiched in between them. A space-cilling model of this structure, called hexagonal close-packed is constituted of a sphere on a flat surface surrounded in the same plane by six identical spheres as closely as possible. Three spheres are then placed overt the first layer so that they touch each other and represent the second layer so that they touch each other and present the second layer. Each one of the three spheres touches three spheres of the bottom layer. Finally, the second layer is converted with a third layer identical to the bottom layer in relative position. Assume the radius of every sphere to be r . The number of atom in this hcp unit cell is (a)4 (b)6 (c)12 (d)17

In a hexaonal system system of cycstals, a frequently encountered arrangement of atoms is described as a hexagonal prism. Here, the top and bottom of the cell are refular hexagons, and three atoms are sandwiched in between them. A space-cilling model of this structure, called hexagonal close-paked is constituted of a sphere on a flat surface surrounded in the same plane by six identical spheres as closely as possible. Three spherres are then placed overt the first layer so that they toych each other and represent the second layer so that they toych each other and present the second layer. Each one of the three spheres touches three spheres of the bottom layer. Finally, the second layer is convered with a third layer identical to the bottom layer in relative position. Assume the radius of every sphere to be r . The number of atom in this hcp unit cell is

In a hexaonal system system of cycstals, a frequently encountered arrangement of atoms is described as a hexagonal prism. Here, the top and bottom of the cell are refular hexagons, and three atoms are sandwiched in between them. A space-cilling model of this structure, called hexagonal close-paked is constituted of a sphere on a flat surface surrounded in the same plane by six identical spheres as closely as possible. Three spherres are then placed overt the first layer so that they toych each other and represent the second layer so that they toych each other and present the second layer. Each one of the three spheres touches three spheres of the bottom layer. Finally, the second layer is convered with a third layer identical to the bottom layer in relative position. Assume the radius of every sphere to be r . The empty space in this hcp unit cell is (a) 74% (b) 48.6% (c) 32% (d) 26%

In hexagonal system of crystals, a frequently encountered arrangement of atoms is described as a hexagonal prism. Here, the top and bottom of the cell are regular hexagons and three atoms are sandwiched in between them. A space -filling model of this structure, called hexagonal close-packed (HCP), is consituted of a sphere on a flat surface surrouneded in the same plane by six identical spheres as closely possible. Three sphere are then palces over the first layer so that they touch each other and represent second layer is covered with third layer that is identical to the bottom layer in relative position. Assume radius of enery sphere to be r. The number of atoms in the HPC unit cell is :

In a hexagonal crystal:

Draw a regular hexagon of side 5 cm.

The number of atoms present in a hexagonal close-packed unit cell is:

The number of atoms present in a hexagonal close-packed unit cell is:

In a regular hexagon ABCDEF, vec(AE)

VMC MODULES ENGLISH-THE SOLID STATE-JEE Advance ( Archive )
  1. In a solid AB having the NaCl structure, A atom occupies the corners o...

    Text Solution

    |

  2. A substance A(x)B(y) crystallizes in a face-centred cubic lattice in ...

    Text Solution

    |

  3. You are given marbles of diameter 10mm. They are to be placed such tha...

    Text Solution

    |

  4. The crystal AB (rock salt structure) has molecular weight 6.023 y u, w...

    Text Solution

    |

  5. Which of the following fcc structure contain cations in alternate tetr...

    Text Solution

    |

  6. The edge length of unit cell of a metal having molecular weight 75 g m...

    Text Solution

    |

  7. An element crystallizes in fcc lattice having edge length 400 pm Calcu...

    Text Solution

    |

  8. Match the crystal system/unit cells mentioned in Column I with their c...

    Text Solution

    |

  9. In hexagonal system of crystals, a frequently encountered arrangement ...

    Text Solution

    |

  10. In hexagonal systems of crystals, a frequently encountered arrangement...

    Text Solution

    |

  11. In hexagonal systems of crystals, a frequently encountered arrangement...

    Text Solution

    |

  12. The corrent statement regarding defects is solids in solids is

    Text Solution

    |

  13. The packing efficiency of the two dimensional square unit cell shown b...

    Text Solution

    |

  14. A compound M(p)X(q) has cubic close packing (ccp) arrangement of X. It...

    Text Solution

    |

  15. The arrangement of X^(ɵ) ions around A^(o+) ion in solid AX is given i...

    Text Solution

    |

  16. If the unit cell of a mineral has cubic close packed (ccp) array of ox...

    Text Solution

    |

  17. Which of the following statements is(are) correct?

    Text Solution

    |

  18. The CORRECT statements (s) for cubic close packed (ccp) three dimensio...

    Text Solution

    |

  19. A crystalline solid of a pure substance has a face-centred cubic struc...

    Text Solution

    |

  20. Consider an ionic solid MX with NaCl structure. Construct a new struct...

    Text Solution

    |