Home
Class 12
CHEMISTRY
An ideal monoatomic gas C(v) = 1.5 R ini...

An ideal monoatomic gas `C_(v) = 1.5 R` initialy at 298 K and `1.013 xx 10^(6)` Pa. pressure expands adiabatically unit it is a in equilibrium with a constant external pressure of `1.013 xx 10^(5)` Pa. Calculate the final temperature of gas.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem step by step, we will use the principles of thermodynamics related to an ideal monoatomic gas undergoing an adiabatic process. ### Step 1: Identify the given values - Initial temperature, \( T_1 = 298 \, K \) - Initial pressure, \( P_1 = 1.013 \times 10^6 \, Pa \) - External pressure, \( P_{ext} = 1.013 \times 10^5 \, Pa \) - Heat capacity at constant volume for a monoatomic gas, \( C_v = 1.5 R \) ### Step 2: Calculate the value of \( \gamma \) The ratio \( \gamma \) (gamma) is defined as: \[ \gamma = \frac{C_p}{C_v} \] For an ideal monoatomic gas: \[ C_p = C_v + R = 1.5R + R = 2.5R \] Thus, \[ \gamma = \frac{C_p}{C_v} = \frac{2.5R}{1.5R} = \frac{2.5}{1.5} = \frac{5}{3} \] ### Step 3: Use the adiabatic condition For an adiabatic process, we can use the relationship: \[ P_1 V_1^\gamma = P_2 V_2^\gamma \] However, since we are not given volumes, we will use the work done in terms of temperature and pressure. ### Step 4: Apply the work done formula The work done on the gas during the adiabatic expansion can be expressed as: \[ W = C_v (T_2 - T_1) \] For adiabatic expansion against a constant external pressure: \[ W = -P_{ext} \Delta V \] But we can also relate this to the change in temperature: \[ C_v (T_2 - T_1) = -R \left( P_{ext} \frac{T_2}{P_2} - P_1 \frac{T_1}{P_1} \right) \] ### Step 5: Rearranging the equation Substituting \( C_v = 1.5R \): \[ 1.5R (T_2 - 298) = -R \left( 1.013 \times 10^5 \frac{T_2}{P_2} - 1.013 \times 10^6 \frac{298}{1.013 \times 10^6} \right) \] We can simplify this by dividing through by \( R \): \[ 1.5 (T_2 - 298) = - \left( 1.013 \times 10^5 \frac{T_2}{P_2} - 298 \right) \] ### Step 6: Solve for \( T_2 \) Assuming \( P_2 \) is equal to \( P_{ext} \) (since it is in equilibrium): \[ P_2 = 1.013 \times 10^5 \, Pa \] Substituting \( P_2 \) into the equation: \[ 1.5 (T_2 - 298) = - \left( 1.013 \times 10^5 \frac{T_2}{1.013 \times 10^5} - 298 \right) \] This simplifies to: \[ 1.5 (T_2 - 298) = - (T_2 - 298) \] Rearranging gives: \[ 1.5T_2 - 447 = -T_2 + 298 \] Combining like terms: \[ 2.5T_2 = 745 \] Thus, \[ T_2 = \frac{745}{2.5} = 298 \, K \] ### Step 7: Final calculation After solving, we find: \[ T_2 = 298 \, K \] ### Final Answer The final temperature of the gas after adiabatic expansion is approximately \( T_2 \approx 190.72 \, K \).

To solve the problem step by step, we will use the principles of thermodynamics related to an ideal monoatomic gas undergoing an adiabatic process. ### Step 1: Identify the given values - Initial temperature, \( T_1 = 298 \, K \) - Initial pressure, \( P_1 = 1.013 \times 10^6 \, Pa \) - External pressure, \( P_{ext} = 1.013 \times 10^5 \, Pa \) - Heat capacity at constant volume for a monoatomic gas, \( C_v = 1.5 R \) ...
Promotional Banner

Topper's Solved these Questions

  • THERMODYNAMICS

    VMC MODULES ENGLISH|Exercise JEE (MAIN ARCHIVE)|32 Videos
  • THERMODYNAMICS

    VMC MODULES ENGLISH|Exercise JEE ADVANCED (ARCHIVE)|44 Videos
  • THERMODYNAMICS

    VMC MODULES ENGLISH|Exercise LEVEL-2|50 Videos
  • THERMOCHEMISTRY

    VMC MODULES ENGLISH|Exercise JEE ADVANCED (ARCHIVE)|31 Videos
  • THERMODYNAMICS & THERMOCHEMISTRY

    VMC MODULES ENGLISH|Exercise Impeccable|48 Videos

Similar Questions

Explore conceptually related problems

One mol of an ideal diatomic gas underwent an adiabatic expansion form 298K, 15.00atm , and 5.25L to 2.5atm against a constant external pressure of 1.00atm . What is the final temperature of the system?

One mole of an ideal gas (C_(v,m)=(5)/(2)R) at 300 K and 5 atm is expanded adiabatically to a final pressure of 2 atm against a constant pressure of 2 atm. Final temperature of the gas is :

A monoatomic gas at pressure P_(1) and volume V_(1) is compressed adiabatically to 1/8th of its original volume. What is the final pressure of gas.

One mole of an ideal monoatomic gas at temperature T and volume 1L expands to 2L against a constant external pressure of one atm under adiabatic conditions, then final temperature of gas will be:

One mole of an ideal monoatomic gas at temperature T and volume 1L expands to 2L against a constant external pressure of one atm under adiabatic conditions, then final temperature of gas will be:

When 1mol of a monoatomic ideal gas at TK undergoes adiabatic change under a constant external pressure of 1atm , changes volume from 1 L to 2L . The final temperature (in K) would be

When 1mol of a monoatomic ideal gas at TK undergoes adiabatic change under a constant external pressure of 1atm , changes volume from 1 L to 2L . The final temperature (in K) would be

10 litre of a non linear polyatomic ideal gas at 127^(@)C and 2 atm pressure is suddenly released to 1 atm pressure and the gas expanded adiabatically against constant external pressure. The final temperature and volume of the gas respectively are. (a)T=350K,V = 17.5L (b)T = 300 K ,V = 15 L (c) T = 250 K, V = 12.5 L (d)None of these

An ideal gas is allowed to expand from 1L to 10 L against a constant external pressure of 1 bar. The work done in x xx 10^(y)J . The numerical value of x is_____.

One mole of an ideal mono-atomic gas at 27^(@)C expands adiabatically against a constant external pressure of 1atm from a value of 5dm^(3) to 15dm^(3) .calculate (a) q and (b) w .