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When 1-pentyne (A) is treated with 4N al...

When `1`-pentyne `(A)` is treated with `4N` alcoholic `KOH` at `175^(@)C`, it is converted slowely into an equilibrium mixture of `1.3% 1`-pentyne `(A), 95.2%2`-pentyne `(B)`,and `3.5%` of `1,2`-pentadiene `(C )`. The equilibrium is maintained at `175^(@)C`. Calculate `DeltaG^(Theta)` for the following equilibria.
`B hArr A, DeltaG_(1)^(Theta) = ?`
`B hArr C, DeltaG_(2)^(Theta) = ?`
From the calculated values of `DeltaG_(1)^(Theta)` and `DeltaG_(2)^(Theta)`, indicate the order of stability of `A, B`, and `C`.

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`DeltaG_(1)^(@) = 16 kJ, DeltaG_(2)^(@) = 12.3 kJ`
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When 1 pentyne (A) is treated with 4N alcoholic KOH at 175^(@)C , it is slowly converted into an equilibrium mixture of 1.3% of 1 pentyne (A), 95.2% 2 -pentyne (B) and 3.5% of 1,2 -pentandiene (C ) . The equilibrium was maintained at 175^(@)C . Calculate DeltaG^(Theta) for the following equilibria: B hArr A, DeltaG^(Theta)underset(1) = ? B hArr C, DeltaG^(Theta)underset(2) =? From the calculated value of DeltaG^(Theta)underset(1) and DeltaG^(Theta)underset(2) , indicate the order of stability of A,B and C . Write a reasonable reaction mechanism showing all intermediates leading to A,B and C .

When 1 pentyne (A) is treated with 4N alcoholic KOH at 175^(@)C , it is slowly converted into an equilibrium mixture of 1.3% of 1 pentyne (A), 95.2% 2 -pentyne (B) and 3.5% of 1,2 -pentandiene (C ) . The equilibrium was maintained at 175^(@)C . calculate DeltaG^(Theta) for the following equilibria: B hArr A, DeltaG^(Theta)underset(1) = ? B hArr C, DeltaG^(Theta)underset(2) =? From the calculated value of DeltaG^(Theta)underset(1) and DeltaG^(Theta)underset(2) , indicate the order of stability of A,B and C .

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