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What is the value of k(c) for the reacti...

What is the value of `k_(c)` for the reaction at 1473 K
`I_(2)(g) hArr 2I(g)`
when one mode of iodic gas is introduced into an evacuated one litre flask so that only 5% of it gets dissociated ?

A

0.0105

B

0.046

C

0.034

D

0.5

Text Solution

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The correct Answer is:
To find the value of \( K_c \) for the reaction \( I_2(g) \rightleftharpoons 2I(g) \) at 1473 K, we follow these steps: ### Step 1: Understand the Reaction The reaction involves the dissociation of 1 mole of iodine gas (\( I_2 \)) into 2 moles of iodine atoms (\( I \)). ### Step 2: Initial Conditions We start with 1 mole of \( I_2 \) in a 1-liter flask. Therefore, the initial concentration of \( I_2 \) is: \[ [I_2] = 1 \text{ mole/L} \] And the initial concentration of \( I \) is: \[ [I] = 0 \text{ mole/L} \] ### Step 3: Degree of Dissociation Given that 5% of \( I_2 \) dissociates, we can express this as: \[ \alpha = 0.05 \] This means that 5% of 1 mole of \( I_2 \) dissociates. ### Step 4: Calculate Concentrations at Equilibrium After dissociation, the concentration of \( I_2 \) at equilibrium will be: \[ [I_2] = 1 - \alpha = 1 - 0.05 = 0.95 \text{ moles/L} \] The amount of \( I_2 \) that dissociates is \( 0.05 \) moles, which produces: \[ 2 \times 0.05 = 0.1 \text{ moles of } I \] Thus, the concentration of \( I \) at equilibrium will be: \[ [I] = 0.1 \text{ moles/L} \] ### Step 5: Write the Expression for \( K_c \) The equilibrium constant \( K_c \) for the reaction is given by: \[ K_c = \frac{[I]^2}{[I_2]} \] ### Step 6: Substitute the Equilibrium Concentrations Substituting the equilibrium concentrations into the expression: \[ K_c = \frac{(0.1)^2}{0.95} \] ### Step 7: Calculate \( K_c \) Calculating the value: \[ K_c = \frac{0.01}{0.95} \approx 0.010526 \] ### Step 8: Round the Result Rounding the result gives: \[ K_c \approx 0.0105 \] ### Conclusion The value of \( K_c \) for the reaction at 1473 K is approximately \( 0.0105 \).

To find the value of \( K_c \) for the reaction \( I_2(g) \rightleftharpoons 2I(g) \) at 1473 K, we follow these steps: ### Step 1: Understand the Reaction The reaction involves the dissociation of 1 mole of iodine gas (\( I_2 \)) into 2 moles of iodine atoms (\( I \)). ### Step 2: Initial Conditions We start with 1 mole of \( I_2 \) in a 1-liter flask. Therefore, the initial concentration of \( I_2 \) is: \[ ...
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