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The vapour density of N(2)O(4) at a cert...

The vapour density of `N_(2)O_(4)` at a certain temperature is `30`. Calculate the percentage dissociation of `N_(2)O_(4)` this temperature.

A

0.535

B

0.6

C

0.745

D

0.645

Text Solution

Verified by Experts

The correct Answer is:
A

Normal molecular mass of `N_(2)O_(4) = 28 + 64 = 92`
Normal vapour density (V.D before dissociation)
`(D) =` Normal moleculer mass/`2 = 92/2 = 46`
Vapour density after dissociation `(d) = 30`
`N_(2)O_(4)(g) rarr 2NO_(2)(g)`
Degree of dissociation (x) = `D-d/d(n-1) = 46-30/30(2-1) = 16/30xx1 = 0.535 implies % = 53.5%`
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