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In a reaction A to B the rate of react...

In a reaction ` A to B` the rate of reaction increases two times on increasing the concentration of the reactant four times, then order of reaction is

A

0

B

2

C

`1//2`

D

`-1//2`

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The correct Answer is:
To determine the order of the reaction \( A \rightarrow B \) based on the given information, we can follow these steps: ### Step 1: Understand the relationship between rate and concentration The rate of a reaction can be expressed as: \[ \text{Rate} = k [A]^n \] where \( k \) is the rate constant, \( [A] \) is the concentration of reactant A, and \( n \) is the order of the reaction with respect to A. ### Step 2: Set up the initial and final conditions Let the initial rate of the reaction be \( R \) when the concentration of A is \( [A] \). According to the problem, when the concentration of A is increased four times (i.e., \( [A] \) becomes \( 4[A] \)), the rate of reaction doubles (i.e., \( R \) becomes \( 2R \)). ### Step 3: Write the rate equations for both conditions 1. Initial condition: \[ R = k [A]^n \quad \text{(1)} \] 2. Final condition with increased concentration: \[ 2R = k (4[A])^n \quad \text{(2)} \] ### Step 4: Substitute and simplify From equation (1), we can express \( R \): \[ R = k [A]^n \] Substituting this into equation (2): \[ 2(k [A]^n) = k (4[A])^n \] This simplifies to: \[ 2 = k (4^n) \frac{[A]^n}{k [A]^n} \] Cancelling \( k [A]^n \) from both sides gives: \[ 2 = 4^n \] ### Step 5: Solve for \( n \) We can rewrite \( 4^n \) as \( (2^2)^n = 2^{2n} \): \[ 2 = 2^{2n} \] This implies: \[ 2^1 = 2^{2n} \] Equating the exponents gives: \[ 1 = 2n \implies n = \frac{1}{2} \] ### Conclusion The order of the reaction with respect to A is \( \frac{1}{2} \). ---

To determine the order of the reaction \( A \rightarrow B \) based on the given information, we can follow these steps: ### Step 1: Understand the relationship between rate and concentration The rate of a reaction can be expressed as: \[ \text{Rate} = k [A]^n \] where \( k \) is the rate constant, \( [A] \) is the concentration of reactant A, and \( n \) is the order of the reaction with respect to A. ...
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