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The half-life of a reaction is halved as...

The half-life of a reaction is halved as the initial concentration of the reaction is doubled. The order of the reaction is

A

0.5

B

1

C

2

D

0

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The correct Answer is:
To determine the order of the reaction based on the information provided, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding Half-Life in Relation to Reaction Order**: The half-life (\(t_{1/2}\)) of a reaction is the time required for the concentration of a reactant to decrease to half its initial concentration. The relationship between half-life and concentration depends on the order of the reaction. 2. **Half-Life for Different Orders**: - For a **zero-order reaction**: \[ t_{1/2} = \frac{[A]_0}{2k} \] - For a **first-order reaction**: \[ t_{1/2} = \frac{0.693}{k} \] - For a **second-order reaction**: \[ t_{1/2} = \frac{1}{k[A]_0} \] 3. **Given Condition**: The problem states that the half-life of the reaction is halved when the initial concentration is doubled. This can be expressed mathematically: \[ t_{1/2} \text{ (new)} = \frac{1}{2} t_{1/2} \text{ (original)} \] Let the original concentration be \( [A]_0 \) and the new concentration be \( 2[A]_0 \). 4. **Applying the Condition to the Half-Life Expressions**: - For a second-order reaction, substituting the new concentration: \[ t_{1/2} \text{ (new)} = \frac{1}{k(2[A]_0)} = \frac{1}{2k[A]_0} \] - The original half-life is: \[ t_{1/2} \text{ (original)} = \frac{1}{k[A]_0} \] - Thus, we have: \[ \frac{1}{2k[A]_0} = \frac{1}{2} \left(\frac{1}{k[A]_0}\right) \] 5. **Conclusion**: Since the relationship holds true, we can conclude that the reaction is second-order. Therefore, the order of the reaction is **2**. ### Final Answer: The order of the reaction is **second order**. ---

To determine the order of the reaction based on the information provided, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding Half-Life in Relation to Reaction Order**: The half-life (\(t_{1/2}\)) of a reaction is the time required for the concentration of a reactant to decrease to half its initial concentration. The relationship between half-life and concentration depends on the order of the reaction. 2. **Half-Life for Different Orders**: ...
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