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The rate constant for a chemical reactio...

The rate constant for a chemical reaction has unit litre `mol^(-1) sec^(-1)`. Find the order of the reaction.

A

0

B

1

C

2

D

3

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The correct Answer is:
To determine the order of the reaction based on the given unit of the rate constant, we can follow these steps: ### Step 1: Understand the units of the rate constant The unit of the rate constant (k) is given as \( \text{litre mol}^{-1} \text{sec}^{-1} \). ### Step 2: Recall the formula for the units of the rate constant The unit of the rate constant for a reaction of order \( n \) is given by: \[ k = \text{concentration}^{(1-n)} \cdot \text{time}^{-1} \] In terms of molarity (moles per litre), this can be expressed as: \[ k = \left( \text{mol} \cdot \text{L}^{-1} \right)^{(1-n)} \cdot \text{sec}^{-1} \] ### Step 3: Substitute the units into the formula Substituting the units into the formula, we get: \[ k = \left( \text{mol} \cdot \text{L}^{-1} \right)^{(1-n)} \cdot \text{sec}^{-1} = \text{mol}^{(1-n)} \cdot \text{L}^{-(1-n)} \cdot \text{sec}^{-1} \] ### Step 4: Compare with the given unit We know that the given unit of the rate constant is \( \text{L} \cdot \text{mol}^{-1} \cdot \text{sec}^{-1} \). ### Step 5: Set up the equation From the comparison, we can set up the following equations for the exponents: 1. For moles: \( 1 - n = -1 \) 2. For seconds: The exponent for time is already \( -1 \). ### Step 6: Solve for \( n \) From the first equation: \[ 1 - n = -1 \implies n = 2 \] ### Conclusion The order of the reaction is \( n = 2 \), which indicates that it is a second-order reaction. ### Summary of the solution: The order of the reaction is 2, as the unit of the rate constant \( \text{L} \cdot \text{mol}^{-1} \cdot \text{sec}^{-1} \) corresponds to a second-order reaction. ---

To determine the order of the reaction based on the given unit of the rate constant, we can follow these steps: ### Step 1: Understand the units of the rate constant The unit of the rate constant (k) is given as \( \text{litre mol}^{-1} \text{sec}^{-1} \). ### Step 2: Recall the formula for the units of the rate constant The unit of the rate constant for a reaction of order \( n \) is given by: \[ ...
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