Home
Class 12
CHEMISTRY
Consider the kinetic data given in the f...

Consider the kinetic data given in the following table for the reaction `A+B+C rarr` Product.

The rate of the reaction for `[A] =0.15" mol dm"^(-3), [B]=0.25" mol dm"^(-3) and [C] =0.15" mol dm"^(-3)`, is found to be `Y xx 10^(-5)" mol dm"^(-3) s^(-1)`. The value of Y is ____.

Text Solution

Verified by Experts

`r=k[A]^(x)[B]^(y) [C]^(z)`
`6xx10^(-5)=k (0.2)^(x) (0.1)^(y) (0.1)^(z)" ……(i)"`
`6xx10^(-5)=k (0.2)^(x) (0.2)^(y) (0.1)^(z)" ……..(ii)"`
`1.2xx10^(-4)=k (0.2)^(x) (0.1)^(y) (0.2)^(z)" …….(iii)"`
`9xx10^(-5) =k (0.3)^(x) (0.1)^(y) (0.1)^(z)" .....(iv)"`
From (i) & (ii) `rArr y=0`
From (i) & (iii) `rArr z=1`
From (i) & (iv) `rArr x=1`
`therefore" "r=k[A] [C]`
From equation (i)
`6xx10^(-5)=k(0.2) (0.1)`
`k=(6xx10^(-5))/(2xx10^(-2))=3xx10^(-3)" "therefore r=3xx10^(-3) [A] [C]`
For `[A] =0.15" mol dm"^(-3), [B] =0.25" mol dm"^(-3) & [C] =0.15" mol dm"^(-3)`
`r=3xx10^(-3)xx0.15xx0.15`
`r=6.75xx10^(-5)" "therefore y=6.75`
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL KINETICS

    VMC MODULES ENGLISH|Exercise JEE Main (Archive)|56 Videos
  • CHEMICAL EQUILIBRIUM

    VMC MODULES ENGLISH|Exercise IN-CHAPTER EXERCISE - G|10 Videos
  • CHEMICAL THERMODYNAMICS

    VMC MODULES ENGLISH|Exercise IN - CHAPTER EXERCISE - L|10 Videos

Similar Questions

Explore conceptually related problems

The following rate data were obtained at 300 K for the reaction 2A +B to C +D Calculate the rate of formation of D when : [A]=0.5 mol L^(-) and [B]=0.2 mol L^(-)

For a first order for the reaction A rarr products : the rate of reaction at [A]=0.2 M is 1.0 xx 10^(-3) mol L^(-1)s^(-1) . The reaction will occur to 75% completion in .

In a first order reaction, the concentration of the reactant decreases form 800 "mol dm"^(-3) to 50 "mol dm"^(-3) in 2 xx 10^(4) s . The rate constant of the reaction (in s^(-1) ) is

For a first-order reaction A rarr B the reaction rate at reactant concentration of 0.10 M is found to be 2.0 xx 10^(-5) "mol" L^(-1) s^(-1) . The half-life period of the reaction is

For a first-order reaction A rarr B the reaction rate at reactant concentration of 0.01 M is found to be 2.0 xx 10^(-5) "mol" L^(-1) s^(-1) . The half-life period of the reaction is

For a first order reaction A to B the reaction rate at reactant concentration of 0.01 M is found to be 2.0 xx 10 ^-5mol L^(-1) s^(-1) . The half-life period of the reaction is

The rate constant for the reaction in gaseous phase O+O_(3) rarr 2O_(2) is 8.0xx10^(-15)" cm"^(3)" molecule"^(-1) s^(-1) at 298 K. Corresponding value in dm^(3)" mol"^(-1) s^(-1) is :

For the reaction 2X+Y+Z to X_2 YZ , the rate equation is : Rate =k [X] [Y]^2 with k = 3.0 xx 10^(-6) mol^(-2) L^(2) s^(-) If[X]=0.1 mol L^(-) ,[Y]=0.2 mol L-and [Z]=0.7 mol L^(-) , determine the initial rate of reaction.

VMC MODULES ENGLISH-CHEMICAL KINETICS -JEE Advanced (Archive)
  1. For the given reaction, A + B rarr Products Following data are given ...

    Text Solution

    |

  2. 2X(g) rarr 3Y(g)+2Z(g) {:("Time (in min)",0,100,200,):} |{:("Parti...

    Text Solution

    |

  3. Ag^(+) + NH(3) ltimplies [Ag(NH(3))]^(+), k(1)=6.8 xx 10^(-5) [Ag(NH...

    Text Solution

    |

  4. Conisder a reaction aG+bH rarr Products. When concentration of both th...

    Text Solution

    |

  5. Under the same reaction conditions, the intial concentration of 1.386 ...

    Text Solution

    |

  6. For a first order reaction A rarr P, the temperature (T) dependent rat...

    Text Solution

    |

  7. The concentration of R in the reaction R rarr P was measured as a func...

    Text Solution

    |

  8. For the first order reaction 2N(2)O(5)(g) rarr 4NO(2)(g) + O(2)(g)

    Text Solution

    |

  9. An organic compound undergoes first decompoistion. The time taken for ...

    Text Solution

    |

  10. In the reaction, P+Q rarr R+S the time taken for 75% reaction of P i...

    Text Solution

    |

  11. For the elementary reaction MrarrN, the rate of disappearance of M inc...

    Text Solution

    |

  12. A closed vessel with rigid walls contains 1 mole of .(92)^(238)U and 1...

    Text Solution

    |

  13. According to the Arrhenius equation,

    Text Solution

    |

  14. A plot of the number of neutrons (n) against the number of protons (p...

    Text Solution

    |

  15. In a bimolecular reaction, the steric factor P was experimentally dete...

    Text Solution

    |

  16. For a first order reaction A(g)rarr2B(g)+C(g) at constant volume and 3...

    Text Solution

    |

  17. For a first order reaction A(g) rarr 2B(g) + C(g) at constant volume a...

    Text Solution

    |

  18. In the decay sequence, {:(238),(92):}Uoverset(-x(1))rarr{:(234),(90)...

    Text Solution

    |

  19. Consider the kinetic data given in the following table for the reactio...

    Text Solution

    |

  20. The decomposition reaction 2N(2)O(5) (g) rarr 2N(2) O(4) (g) +O(2) (g)...

    Text Solution

    |