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Following 1^@ amine has chiral carbon as...

Following `1^@` amine has chiral carbon as indicated
`H-undersetunderset(C_2H_5)|oversetoverset(CH_3)|(C^(***))-NH_2`
This on reaction with (`NaNO_2` + HCI) forms

A

`1^(@) ` alcohol with retention of configuration

B

`2^(@) ` alcohol with inverted configuration

C

Racemic mixture of `2^@ ` alcohol

D

race mixture of `1^@` alcohol

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AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the given structure of the amine and its reaction with sodium nitrite (NaNO2) in the presence of hydrochloric acid (HCl). ### Step-by-Step Solution: 1. **Identify the Structure of the Amine**: The amine is represented as: ``` H | C2H5-C-CH3 | NH2 ``` Here, the carbon atom attached to the `NH2` group is a chiral center because it is bonded to four different groups: `H`, `C2H5`, `CH3`, and `NH2`. 2. **Reaction with NaNO2 and HCl**: When a primary amine reacts with sodium nitrite (NaNO2) in the presence of hydrochloric acid (HCl), it undergoes diazotization. The reaction can be summarized as follows: - The amine (R-NH2) reacts with HCl to form the ammonium salt (R-NH3^+ Cl^-). - The ammonium salt then reacts with NaNO2 to form a diazonium salt (R-N2^+ Cl^-). 3. **Formation of the Diazotization Product**: The diazonium salt formed is: ``` C2H5-C-CH3 | N2^+ Cl^- ``` This is a stable compound at low temperatures and can be used for further reactions. 4. **Conclusion**: The final product of the reaction of the given chiral amine with NaNO2 and HCl is the corresponding diazonium salt. ### Final Answer: The reaction of the given chiral amine with NaNO2 and HCl forms a diazonium salt. ---
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