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The normal boiling point of an ether is ...

The normal boiling point of an ether is 307 K. Ether is to be a stored in aluminium drums that can withstand a pressure of 10 atm. If `Delta H_("vaporisation")` of ether is 27 kJ `mol^(-1)` at its boiling point, the maximum temperature to which the drums of ether could be safely exposed is

A

293 K

B

315 K

C

392 K

D

420 K

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To solve the problem, we need to determine the maximum temperature to which the aluminum drums containing ether can be safely exposed, given that they can withstand a pressure of 10 atm. We will use the Clausius-Clapeyron equation to relate the vapor pressure of the ether to its temperature and enthalpy of vaporization. ### Step-by-Step Solution: 1. **Identify Given Values:** - Normal boiling point of ether (T1) = 307 K - Vapor pressure at boiling point (P1) = 1 atm (since it is the boiling point) - Maximum pressure (P2) = 10 atm ...
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