Home
Class 12
CHEMISTRY
Acetaldehyde when treated with dilute Na...

Acetaldehyde when treated with dilute `NaOH` gives.

A

`CH_(3)CH_(2)OH`

B

`CH_(3)COOH`

C

`beta-`hydroxybutanal

D

Ethane

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the reaction of acetaldehyde with dilute NaOH, we will follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactant**: The reactant in this case is acetaldehyde, which has the molecular formula CH3CHO. 2. **Understand the Reaction Conditions**: The reaction is conducted in the presence of dilute NaOH. This indicates that we are likely dealing with an aldol condensation reaction. 3. **Recognize the Aldol Reaction**: In an aldol reaction, aldehydes or ketones with at least one alpha hydrogen can react with a base to form a beta-hydroxy aldehyde or ketone. Acetaldehyde has alpha hydrogens (the hydrogens attached to the carbon adjacent to the carbonyl group). 4. **Formation of Enolate Ion**: The hydroxide ion (OH-) from NaOH will abstract one of the alpha hydrogens from acetaldehyde, forming an enolate ion. The structure of the enolate ion can be represented as: \[ CH_2=C(OH)CHO \] 5. **Nucleophilic Attack**: The enolate ion then acts as a nucleophile and attacks the carbonyl carbon of another molecule of acetaldehyde. This leads to the formation of a beta-hydroxy aldehyde. 6. **Final Product Formation**: After the nucleophilic attack, the resulting compound is a beta-hydroxybutanal (also known as 3-hydroxybutanal). The structure can be represented as: \[ CH_3-CH(OH)-CH_2-CHO \] 7. **Conclusion**: Therefore, the product formed when acetaldehyde is treated with dilute NaOH is beta-hydroxybutanal. ### Final Answer: Acetaldehyde when treated with dilute NaOH gives **beta-hydroxybutanal**.
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • ALDEHYDES,KETONES & CARBOXYLIC ACIDS

    VMC MODULES ENGLISH|Exercise IN-CHAPTER EXERCISE-E|10 Videos
  • ALDEHYDES,KETONES & CARBOXYLIC ACIDS

    VMC MODULES ENGLISH|Exercise IN-CHAPTER EXERCISE-F|10 Videos
  • ALDEHYDES,KETONES & CARBOXYLIC ACIDS

    VMC MODULES ENGLISH|Exercise IN-CHAPTER EXERCISE-C|10 Videos
  • ALCOHOLS, PHENOLS & ETHERS

    VMC MODULES ENGLISH|Exercise Impeccable|100 Videos
  • AMINES

    VMC MODULES ENGLISH|Exercise IN CHAPTER EXERCISE H|10 Videos

Similar Questions

Explore conceptually related problems

Acetylene when treated with dilute HCl at 60^(@)C(333K) in presence of HgCl_(2) produces-

What happens when Aluminium is treated with dilute NaOH .

Knowledge Check

  • Which compound is obtained when acetaldehyde is treated with dilute solution of caustic soda ?

    A
    Sodium acetate
    B
    Resinous mass
    C
    Aldol
    D
    Ethyl acetate
  • Similar Questions

    Explore conceptually related problems

    Hydrogen gas is not released when Zn is treated with dilute Nitric acid. Comment.

    An aqueous solution of a mixture of two inorganic salts when treated with dilute HCl, gave a precipitate (P) and a filtrate (Q). The precipitate (P) was found to dissolve in hot water. The filtrate (Q) remained unchanged, when treated with H_(2)S in a dilute mineral acid medium. However, it gave a green precipitate (R) in with H_(2)S in ammoniacal medium. The precipitate (R) gave a coloured solution (S), when treated with H_(2)O_(2) in an aqueous NaOH medium. The coloured solution (S) contains

    An aqueous solution of a mixture of two inorganic salts when treated with dilute HCl, gave a precipitate (P) and a filtrate (Q). The precipitate (P) was found to dissolve in hot water. The filtrate (Q) remained unchanged, when treated with H_(2)S in a dilute mineral acid medium. However, it gave a green precipitate (R) H_(2)S in an ammoniacal medium. The precipitate (R) gave a coloured solution (S), when treated with H_(2)O_(2) in an aqueous NaOH medium. The precipitate P contains

    Aniline when treated with conc. HNO_3 gives

    When a mixture of benzaldehyde and acetophenone is treated with dilute NaOH at 293 K , it form

    The number of salts formed by telluric acid when treated with strong base NaOH is/are.

    Acetanilide when treated with bromine in acetic acid gives: